1: With CF3O3S(1-)*C45H39N2OPRh(1+); benzo[1,3,2]dioxaborole in tetrahydrofuran T=0°C; Inert atmosphere; 2: With dihydrogen peroxide; sodium hydroxide in ethanol; water T=0 - 20°C; optical yield given as percent eeenantioselective reaction;
alkaline hydrogen peroxide; lithium triethylborohydride in tetrahydrofuran T=0°C; 1 h; var. time, var. reducing agent, isotope effect; Rate constantProduct distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 48, # 18 p. 3091 - 3096
