3,5-双(三氟甲基)苯硼酸频那醇酯合成路线 （共 14 条）
反应条件
copper(l) iodide; 1,10-phenanthroline; potassium iodide in methanol; water T=80°C; 3 h; High pressure;
参考文献
Organic Letters, , vol. 15, # 1 p. 140 - 143
反应条件
copper(ll) bromide in methanol T=80°C;
参考文献
Murphy, Jaclyn M.; Liao, Xuebin; Hartwig, John F.
Journal of the American Chemical Society, 2007 , vol. 129, # 50 p. 15434 - 15435
反应条件
1: With sodium periodate in tetrahydrofuran; water 0.25 h; 2: With hydrogenchloride in tetrahydrofuran; water 4 h;
参考文献
Murphy, Jaclyn M.; Tzschucke, C. Christoph; Hartwig, John F.
Organic Letters, 2007 , vol. 9, # 5 p. 757 - 760
反应条件
1: tBuCH2CH2B(H)NiPr2; 3,5-ditrifluoromethylbenzenediazonium tetrafluoroborate With biscyclopentadienyliron(II) in acetonitrile
T=20°C; 2.5 h;
2: With methanol in acetonitrile
T=0 - 20°C; 1 h;
3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile
T=20°C; 4 h; Reagent/catalyst;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 58 ;
反应条件
2,2'-bipyridine-4,4'-dicarboxylic acid-iridium complex in 2-methyl cyclohexane
T=80°C; 13 h;
参考文献
Tagata, Tsuyoshi; Nishida, Mayumi; Nishida, Atsushi
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 10 p. 1662 - 1666
反应条件
Cp*Rh(η4-C6Me6) in cyclohexane
T=150°C; 10 h;
参考文献
Tse; Cho; Smith 3rd.
Organic letters, 2001 , vol. 3, # 18 p. 2831 - 2833
反应条件
in ethanol
T=20°C; 0.5 h;
参考文献
Takagi, Jun; Yamakawa, Tetsu
Tetrahedron Letters, 2013 , vol. 54, # 2 p. 166 - 169
反应条件
in diethyl ether
T=20°C; 4 h; Inert atmosphere;
参考文献
Marciasini, Ludovic D.; Vaultier, Michel; Pucheault, Mathieu
Tetrahedron Letters, 2014 , vol. 55, # 10 p. 1702 - 1705
反应条件
bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I) in cyclohexane
(Schlenk, N2 atm.) the soln. in cyclohexane was stirred at room temp. overnight; Kugelrohr distillation;
参考文献
Boller, Timothy M.; Murphy, Jaclyn M.; Hapke, Marko; Ishiyama, Tatsuo; Miyaura, Norio; Hartwig, John F.
Journal of the American Chemical Society, 2005 , vol. 127, # 41 p. 14263 - 14278
反应条件
[Ir(C8H12)(OCH3)]2; 4,4'-di-tertbutylpyridine in further solvent(s)
(N2); heating mixt. of iridium compd., bipyridine deriv., benzene deriv., dodecane and silylborane deriv. at 80°C for 4 h; cooling to room temp., chromy. (silica gel, diethyl ether in hexane (gradient from 0percent to 5percent)), NMR;
参考文献
Boebel, Timothy A.; Hartwig, John F.
Organometallics, 2008 , vol. 27, # 22 p. 6013 - 6019
