3,5-双(三氟甲基)苯硼酸频那醇酯合成路线 （共 14 条）
反应条件
iridium(hydrotris(pyrazolyl)borate)(1,5-cyclooctadiene)
T=120°C; 16 h;
参考文献
Murata, Miki; Odajima, Hiroki; Watanabe, Shinji; Masuda, Yuzuru
Bulletin of the Chemical Society of Japan, 2006 , vol. 79, # 12 p. 1980 - 1982
反应条件
1.1: tetrafluoroboric acid / water / 0.17 h / 0 °C
1.2: 1 h / 0 °C
1.3: 2.5 h / 20 °C / |Inert atmosphere
2.1: diethyl ether / 4 h / 20 °C
View Scheme
参考文献
Marciasini, Ludovic D.; Richy, Nicolas; Vaultier, Michel; Pucheault, Mathieu
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 6 p. 1083 - 1088
反应条件
in perdeuterocyclohexane
(Schlenk; N2 atm.) a soln. of complex and cyclooctene in cyclohexane-d12and methylcyclohexane-d14 was reacted with 20 equiv of (CF3)2C6H4 at 0. degree.C; detected by NMR spectra;
参考文献
Boller, Timothy M.; Murphy, Jaclyn M.; Hapke, Marko; Ishiyama, Tatsuo; Miyaura, Norio; Hartwig, John F.
Journal of the American Chemical Society, 2005 , vol. 127, # 41 p. 14263 - 14278
反应条件
in perdeuterocyclohexane
Kinetics; at 25°C for 48 h; detd. by 1H and 31P NMR;
参考文献
Chotana, Ghayoor A.; Vanchura II, Britt A.; Tse, Man Kin; Staples, Richard J.; Maleczka Jr., Robert E.; Smith III, Milton R.
Chemical Communications, 2009 , # 38 p. 5731 - 5733
