双(三-o-甲苯磷)钯(0)合成路线 （共 9 条）
反应条件
in methanol 3 h; Heating / reflux;
参考文献
JOHNSON MATTHEY PLC
Patent: WO2007/29031 A1, 2007 ;
Location in patent: Page/Page column 5 ;
反应条件
in tetrahydrofuran T=20°C; 2 h;
参考文献
Harding, Brennen A.; Melvin, Patrick R.; Dougherty, William; Kassel, Scott; Goodson, Felix E.
Organometallics, 2013 , vol. 32, # 12 p. 3570 - 3573
反应条件
in further solvent(s) (Ar); addn. of phosphine to soln. of Pd complex in hepta-1,6-diene, evapn. (in vacuo); washing (Et2O), drying (in vacuo); identified by NMR;
参考文献
Krause, Jochen; Cestaric, Guenter; Haack, Karl-Josef; Seevogel, Klaus; Storm, Werner; Poerschke, Klaus-Richard
Journal of the American Chemical Society, 1999 , vol. 121, # 42 p. 9807 - 9823
反应条件
in benzene inert atmosphere; stirring (room temp., 20 h); filtering, evapn., pptn. on Et2O addn. (-30°C); elem. anal.;
参考文献
Paul, Frederic; Patt, Joe; Hartwig, John F.
Organometallics, 1995 , vol. 14, p. 3030 - 3039
反应条件
in benzene addn. of 7 equiv. of phosphine to Pd(0) complex in benzene, 12 h; filtered, addn. of ether, crystn. after several days, identified by x-ray diffraction and 31P-NMR spectroscopy;
参考文献
Paul, Frederic; Patt, Joe; Hartwig, John F.
Journal of the American Chemical Society, 1994 , vol. 116, # 13 p. 5969 - 5970
反应条件
sodium hydroxide in ethanol; toluene N2 atmosphere, addn. of EtOH soln. of NaOH to toluene suspension of Pd complex and phosphane ligand, 90°C (5 h), cooling; filtration, washing (water, EtOH and Et2O), drying (vacuum);
参考文献
European Journal of Inorganic Chemistry, , # 1 p. 29 - 35
反应条件
NaOtBu in tetrahydrofuran 48 percent yield by NMR;
参考文献
Angewandte Chemie - International Edition in English, , vol. 35, # 20 p. 2359 - 2361
反应条件
1: pentane 2: NaOtBu / tetrahydrofuran View Scheme
参考文献
Angewandte Chemie - International Edition in English, , vol. 35, # 20 p. 2359 - 2361
反应条件
in not given byproducts: P(o-tolyl)3; treatment of Pd(P(o-tolyl)3)2 with P(t-Bu)3;
参考文献
Stambuli, James P.; Incarvito, Christopher D.; Buehl, Michael; Hartwig, John F.
Journal of the American Chemical Society, 2004 , vol. 126, # 4 p. 1184 - 1194
