1-溴-4-(三甲基硅基)苯合成路线 （共 43 条）
反应条件
Ph3PAuOTs; camphor-10-sulfonic acid; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in methanol; chloroform T=65°C;
参考文献
Ball, Liam T.; Lloyd-Jones, Guy C.; Russell, Christopher A.
Science (Washington, DC, United States), 2012 , vol. 337, # 6102 p. 1644 - 1648,5
反应条件
in N,N-dimethyl-formamide 5 h; Heating;
参考文献
Walree, Cornelis A. van; Lauteslager, Xavier Y.; Wageningen, Andreas M. A. van; Zwikker, Jan W.; Jenneskens, Leonardus W.
Journal of Organometallic Chemistry, 1995 , vol. 496, # 1 p. 117 - 126
反应条件
1: 60 percent / tetrahydrofuran; hexane / 2 h / 20 °C 2: 91 percent Chromat. / H2O / 0.5 h / 390 °C View Scheme
参考文献
Itami, Kenichiro; Terakawa, Koji; Yoshida, Jun-ichi; Kajimoto, Okitsugu
Journal of the American Chemical Society, 2003 , vol. 125, # 20 p. 6058 - 6059
反应条件
1: With isopropylmagnesium chloride lithium chloride complex in tetrahydrofuran T=0°C; 2: With methanol in tetrahydrofuran Reactivity;
参考文献
Shi, Lei; Chu, Yuanyuan; Knoechel, Paul; Mayr, Herbert
Journal of Organic Chemistry, 2009 , vol. 74, # 7 p. 2760 - 2764
反应条件
1: With isopropylmagnesium chloride lithium chloride complex in tetrahydrofuran T=0°C; 2: With methanol in tetrahydrofuran Reactivity;
参考文献
Shi, Lei; Chu, Yuanyuan; Knoechel, Paul; Mayr, Herbert
Journal of Organic Chemistry, 2009 , vol. 74, # 7 p. 2760 - 2764
反应条件
(i) AlCl3, (ii) /BRN= 2638178/; Multistep reaction;
参考文献
Bhattacharya,S.N. et al.
Journal of the Chemical Society [Section] C: Organic, 1969 , p. 1367 - 1369
反应条件
1: With sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) in toluene 3 h; Heating / reflux; 2: With water in tetrahydrofuran; toluene T=20°C;
参考文献
LG CHEM, LTD.
Patent: WO2007/108666 A1, 2007 ;
Location in patent: Page/Page column 34-35 ;
参考文献
Kohama; Fukugawa
Nippon Kagaku Zasshi, 1958 , vol. 79, p. 1307
Chem.Abstr., 1960 , p. 5525
反应条件
NiCl2((PPh3)P)2 in ethylene glycol dimethyl ether T=80°C; 4 h; Inert atmosphere;
参考文献
Biradar, Deepak B.; Gau, Han-Mou
Chemical Communications, 2011 , vol. 47, # 37 p. 10467 - 10469
反应条件
1: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 1 h, 2.) THF, hexane, a) -78 deg C, 15 min, b) from -78 deg C to RT 2: 95 percent / iodine monochloride / CCl4 / 1.) RT, 30 min, 2.) reflux, 1 h View Scheme
参考文献
Ekhato; Huang
Journal of Labelled Compounds and Radiopharmaceuticals, 1994 , vol. 34, # 3 p. 213 - 220
