(C4H9)4NCl in chloroform Kinetics; byproducts: S(CH2COOH)2, C5H4(CH3)N, PO(C6H5)3; react. of Re complex with pyridine deriv.in CHCl3 in presence of (C4H9)4NCl, UV monitored;
in acetonitrile (inert atm.); addn. of zinc compd. to soln. of rhenium compd. in CH3CN, stirring for 30 min; filtration, evapn., sublimation at 40°C at 1E-1 mbar;
参考文献
Mitterpleininger, Josef K. M.; Szesni, Normen; Sturm, Stefanie; Fischer, Richard W.; Kuehn, Fritz E.
European Journal of Inorganic Chemistry, 2008 , # 25 p. 3929 - 3934
in tetrahydrofuran exclusion of moisture, refluxed for 4 h; cooled, removal of solvent in vac., sublimation at 80°C (CH3ReO3); elem. anal., residue dissolved in THF, filtered, removal of solvent from the filtrate: ((CH3)3SnO)ReO3; elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 372, p. 351 - 370
in acetonitrile (inert atm.); addn. of zinc compd. to soln. of rhenium compd. in CH3CN, stirring for 30 min; filtration, evapn., sublimation at 40°C at 1E-1 mbar;
参考文献
Mitterpleininger, Josef K. M.; Szesni, Normen; Sturm, Stefanie; Fischer, Richard W.; Kuehn, Fritz E.
European Journal of Inorganic Chemistry, 2008 , # 25 p. 3929 - 3934
