5-氧代-1,3,3-三甲基-环己烷甲腈合成路线 （共 21 条）
反应条件
1: With ammonia; hydrogen; potassium carbonate in water T=50 - 80°C; P=135014 Torr; 2: With (1'-14C)-dodecanoic acid in tetrahydrofuran; water T=115°C; P=135014 Torr; TemperaturePressureSolventReagent/catalyst;
参考文献
Wanhua Chemical (Ningbo) Co., Ltd.; WANHUA CHEMICAL GROUP CO., LTD.; Chen, Changsheng; Li, Yuan; Zhao, Wenjuan; Cui, Hongyin; Hua, Weiqi
Patent: US2014/142341 A1, 2014 ;
Location in patent: Paragraph 0062; 0063; 0064 ;
反应条件
ammonia; hydrogen; potassium carbonate in water T=50 - 80°C; P=135014 Torr; TemperatureSolventReagent/catalystPressure;
参考文献
Wanhua Chemical Group Co., Ltd.; Wanhua Chemical (Ningbo) Co., Ltd.; CHEN, Changsheng; LI, Yuan; ZHAO, Wenjuan; CUI, Hongyin; HUA, Weiqi
Patent: EP2743251 A1, 2014 ;
反应条件
ammonia; hydrogen; Raney-type cobalt catalyst T=100°C; 2 h; Product distribution / selectivity;
参考文献
EVONIK DEGUSSA GmbH
Patent: US2009/48466 A1, 2009 ;
Location in patent: Page/Page column 5 ;
反应条件
1: With ammonia; Titanium(IV) oxide T=60°C; 2: With hydrogen; cobalt T=90°C; P=60006 Torr; Product distribution / selectivity;
参考文献
BASF SE
Patent: US2012/245389 A1, 2012 ;
Location in patent: Page/Page column 8 ;
参考文献
Sumitomo Chemical Company, Limited
Patent: US5589596 A1, 1996 ;
反应条件
ammonia; hydrogen T=80 - 130°C; Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2004/20386 A1, 2004 ;
Location in patent: Page/Page column 12-13 ;
反应条件
1: With lithium aluminium tetrahydride in tetrahydrofuran 16 h; Reflux; 2: With water; sodium hydroxide in tetrahydrofuran T=0°C;
参考文献
Chen, Li; Lin, Xianfeng; Qiu, Zongxing; Tang, Guozhi; Wang, Lisha; Wu, Jim Zhen; Yang, Wengang
Patent: US2011/195979 A1, 2011 ;
Location in patent: Page/Page column 20 ;
反应条件
ammonia; hydrogen T=80 - 130°C; Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2004/20386 A1, 2004 ;
Location in patent: Page/Page column 12-13 ;
反应条件
ammonium chloride in water; N,N-dimethyl-formamide
T=80°C; 20 h;
参考文献
Chen, Li; Lin, Xianfeng; Qiu, Zongxing; Tang, Guozhi; Wang, Lisha; Wu, Jim Zhen; Yang, Wengang
Patent: US2011/195979 A1, 2011 ;
Location in patent: Page/Page column 20 ;
反应条件
CaO
T=150 - 175°C; 2 - 3 h;
参考文献
Kunsmann-Keitel, Dagmar Pascale; Braun, Gerold; Munster, Ingo; Mundinger, Klaus; Scherhag, Gunter; Siegel, Wolfgang
Patent: US2004/92761 A1, 2004 ;
Location in patent: Page 2-3 ;
