2-乙炔基-α,α,α-三氟甲苯合成路线 （共 15 条）
反应条件
hydrogen in hexane P=760.051 Torr; chemoselective reaction;
参考文献
Lee, Kyu Hyung; Lee, Byeongno; Lee, Kyu Reon; Yi, Mi Hye; Hur, Nam Hwi
Chemical Communications, 2012 , vol. 48, # 37 p. 4414 - 4416
反应条件
sodium methylate; copper in ethanol T=25°C; 24 h; Schlenk techniqueInert atmosphereSealed tube; regioselective reaction;
参考文献
Zhao, Jie; Niu, Zhiqiang; Fu, Hua; Li, Yadong
Chemical Communications, 2014 , vol. 50, # 16 p. 2058 - 2060
反应条件
NaOC(CH3)3; CH3OH; [(N,N′-bis[2,6-diisopropylphenyl]imidazolin-2-ylidene)CuCl] in tetrahydrofuran 1.0 molpercent Cu-complex, alkyne, diborane, NaOC(CH3)3, CH3OH, THF, -15°C, 24 h, N2 atm.; 83:17 ratio of isomers;
参考文献
Jang, Hwanjong; Zhugralin, Adil R.; Lee, Yunmi; Hoveyda, Amir H.
Journal of the American Chemical Society, 2011 , vol. 133, # 20 p. 7859 - 7871
反应条件
Au nanoparticles covalently bonded to HS/SO3H functionalized periodic mesoporous organosilica (Et) in water T=80°C; 4 h;
参考文献
Zhu, Feng-Xia; Wang, Wei; Li, He-Xing
Journal of the American Chemical Society, 2011 , vol. 133, # 30 p. 11632 - 11640
反应条件
n-butyllithium in tetrahydrofuran; hexane
T=-60 - 20°C;
参考文献
Tanaka, Ken; Nishida, Goushi; Wada, Azusa; Noguchi, Keiichi
Angewandte Chemie - International Edition, 2004 , vol. 43, # 47 p. 6510 - 6512
