3-乙炔基-α,α,α-三氟甲苯合成路线 （共 22 条）
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in N,N-dimethyl-formamide 0.0166667 h; microwave irradiation;
参考文献
Chemistry Letters, , vol. 34, # 1 p. 28 - 29
反应条件
in pentane T=23°C; Irradiation;
参考文献
Canadian Journal of Chemistry, , vol. 73, # 2 p. 191 - 203
反应条件
1: PCl5 2: NaNH2 / liquid ammonia View Scheme
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 50, # 8 p. 1752 - 1756,1424 - 1427
反应条件
1: 1.) n-C4H9Li 2: n-C4H9Li View Scheme
参考文献
Journal of Fluorine Chemistry, , vol. 23, p. 497
反应条件
in pentane T=23°C; Irradiationalso in acetonitrile; Quantum yieldRate constant;
参考文献
Canadian Journal of Chemistry, , vol. 73, # 2 p. 191 - 203
反应条件
T=23°C; Irradiation; Quantum yieldRate constant;
参考文献
Canadian Journal of Chemistry, , vol. 73, # 2 p. 191 - 203
反应条件
NaOC(CH3)3; CH3OH; [(N,N′-bis[2,6-diisopropylphenyl]imidazolin-2-ylidene)CuCl] in tetrahydrofuran 1.0 molpercent Cu-complex, alkyne, diborane, NaOC(CH3)3, CH3OH, THF, -15°C, 24 h, N2 atm.; 89:11 ratio of isomers;
参考文献
Jang, Hwanjong; Zhugralin, Adil R.; Lee, Yunmi; Hoveyda, Amir H.
Journal of the American Chemical Society, 2011 , vol. 133, # 20 p. 7859 - 7871
反应条件
1: With [1,3-bis(diphenylphosphino) propane] dichloronickel(II); diisobutylaluminium hydride in tetrahydrofuran T=0 - 4°C; Inert atmosphere; 2: With water; Potassium sodium tartrate in tetrahydrofuran T=0°C; 0.5 h;
参考文献
Gao, Fang; Hoveyda, Amir H.
Journal of the American Chemical Society, 2010 , vol. 132, # 32 p. 10961 - 10963
反应条件
(i) EtMgBr, (ii) /BRN= 1209228/; Multistep reaction;
参考文献
Hayami,J.-I. et al.
Bulletin of the Chemical Society of Japan, 1973 , vol. 46, p. 954 - 959
反应条件
triethylamine in tetrahydrofuran
T=0 - 20°C;
参考文献
Zablocki, Jeff; Abelman, Matthew; Organ, Michael; Bilokin, Yaroslav; Diamond, Ivan; Arolfo, Maria Pia; Yao, Lina; Fan, Peidong; Elzein, Elfatih; Kalla, Rao; Perry, Thao; Kobayshi, Tetsuya; Lee, Xiaofen; Jiang, Robert
Patent: US2008/32995 A1, 2008 ;
Location in patent: Page/Page column 22 ;
US 20080032995 A1
