4-乙炔基-α,α,α-三氟甲苯合成路线 （共 50 条）
反应条件
tetrafluoroboric acid; 2,4,6-trimethylphenyl iodide; 3-chloro-benzenecarboperoxoic acid in dichloromethane; water; acetonitrile T=50°C; 10 h; Inert atmosphere;
参考文献
Miyamoto, Kazunori; Ochiai, Masahito; Sei, Yoshihisa; Yamaguchi, Kentaro
Journal of the American Chemical Society, 2009 , vol. 131, # 4 p. 1382 - 1383
反应条件
1: With [1,3-bis(diphenylphosphino) propane] dichloronickel(II); diisobutylaluminium hydride in tetrahydrofuran T=0 - 22°C; Inert atmosphere; 2: With water; Potassium sodium tartrate in tetrahydrofuran T=0°C; 0.5 h;
参考文献
Gao, Fang; Hoveyda, Amir H.
Journal of the American Chemical Society, 2010 , vol. 132, # 32 p. 10961 - 10963
反应条件
1,3-dibutyl-4,5-dichloro-imidazole-1,3-divinylsiloxane Pt(0) in tetrahydrofuran T=25°C; 3 h;
参考文献
Lillo, Vanesa; Mata, Jose A.; Segarra, Anna M.; Peris, Eduardo; Fernandez, Elena
Chemical Communications, 2007 , # 21 p. 2184 - 2186
反应条件
bis(1,5-cyclooctadiene)nickel (0); 1,8-diazabicyclo[5.4.0]undec-7-ene in tetrahydrofuran T=0°C; P=760 Torr; 2 h;
参考文献
Saito, Shinichi; Nakagawa, Satomi; Koizumi, Toru; Hirayama, Kyoko; Yamamoto, Yoshinori
Journal of Organic Chemistry, 1999 , vol. 64, # 11 p. 3975 - 3978
反应条件
Au nanoparticles covalently bonded to HS/SO3H functionalized periodic mesoporous organosilica (Et) T=70°C; 1.5 h; neat (no solvent);
参考文献
Zhu, Feng-Xia; Wang, Wei; Li, He-Xing
Journal of the American Chemical Society, 2011 , vol. 133, # 30 p. 11632 - 11640
反应条件
1: 4-trifluoromethyl phenylacetylene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1.5 h; Inert atmosphere; 2: chloroformic acid ethyl ester in tetrahydrofuran; hexane T=20°C; 19 h; Inert atmosphere;
参考文献
O'Rourke, Natasha F.; Wulff, Jeremy E.
Organic and Biomolecular Chemistry, 2014 , vol. 12, # 8 p. 1292 - 1308
反应条件
palladium 10 on activated carbon; oxygen; tetra-(n-butyl)ammonium iodide in 1,4-dioxane T=80°C; P=760.051 Torr; 8 h; Autoclave;
参考文献
Gadge, Sandip T.; Bhanage, Bhalchandra M.
Synlett, 2013 , vol. 24, # 8 art. no. ST-2013-D0181-L, p. 981 - 986
反应条件
bis(1,5-cyclooctadiene)nickel (0); 1,8-diazabicyclo[5.4.0]undec-7-ene in tetrahydrofuran T=0°C; P=760 Torr; 2 h;
参考文献
Saito, Shinichi; Nakagawa, Satomi; Koizumi, Toru; Hirayama, Kyoko; Yamamoto, Yoshinori
Journal of Organic Chemistry, 1999 , vol. 64, # 11 p. 3975 - 3978
反应条件
copper(l) iodide; 1,8-diazabicyclo[5.4.0]undec-7-ene in ethanol 60 h; Inert atmosphereReflux;
参考文献
Wang, Ruiping; Mo, Song; Lu, Yongzhong; Shen, Zengming
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 5 p. 713 - 718
反应条件
copper(l) iodide; 1,8-diazabicyclo[5.4.0]undec-7-ene in ethanol 48 h; Inert atmosphereReflux;
参考文献
Advanced Synthesis and Catalysis, , vol. 353, # 5 p. 713 - 718
