反,反,顺-1,5,9-环十二烷基三烯合成路线 （共 58 条）
反应条件
1: 85 percent / isopropylbenzene hydroperoxide, molybdenum diacetylacetonate / benzene / 1 h / 80 °C 2: 1.) LiI, 2.) H2 / 2.) Raney nickel / 1.) 140 deg C, 4 h, 2.) ethanol, 20 deg C, 1 atm, 30 h View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 7.2 p. 1291 - 1294
Zhurnal Organicheskoi Khimii, , vol. 26, # 7 p. 1497 - 1500
反应条件
1.) PPA; palladium on activated charcoal 1.) 150 deg C, 4 h, 2.) reflux, 15 h; Yield given. Multistep reaction;
参考文献
Zakharkin, L. I.; Zhigareva, G. G.; Pryanishnikov, A. P.; Ovseenko, S. T.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1986 , vol. 35, # 10 p. 2061 - 2064
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1986 , # 10 p. 2256 - 2259
反应条件
dihydrogen peroxide in acetonitrile T=60°C; 5 h;
参考文献
Lin, Kaifeng; Lebedev, Oleg I.; Vana Tendeloo, Gustaaf; Jacobs, Pierre A.; Pescarmona, Paolo P.
Chemistry - A European Journal, 2010 , vol. 16, # 45 p. 13509 - 13518
反应条件
hydrogen; ruthenium trichloride; formaldehyd; 1,6-hexanedioic acid; ethanol; triphenylphosphine in water T=100 - 140°C; P=15001.5 Torr; 24 h;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/30689 A2, 2005 ;
Location in patent: Page/Page column 27-28 ;
反应条件
hydrogen; (o-OC6H4CH3)3PRuCl(PPh3)2 in benzene the reaction was carried out in two steps (beetwen them the reaction mixture was exposed to air); 1.) p=65 psi, 120 deg C, 2 h, 2.) p=70 psi, 95 deg C, 17 h; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 108, p. 743
反应条件
hydrogen T=79.84°C; P=1125.11 Torr;
参考文献
Gaube; David; Sanchayan; Wuchter; Klein
Applied Catalysis A: General, 2011 , vol. 409-410, p. 21 - 27
反应条件
[(Ph3P)2N][Ru6C(CO)16SnCl3]; mesoporous silica MCM-41; hydrogen T=79.85 - 139.85°C; P=22501.8 Torr; 24 h; KineticsProduct distribution; Further Variations:ReagentsTemperatures;
参考文献
Hermans, Sophie; Raja, Robert; Thomas, John M.; Johnson, Brian F. G.; Sankar, Gopinathan; Gleeson, David
Angewandte Chemie - International Edition, 2001 , vol. 40, # 7 p. 1211 - 1215
反应条件
1: isopropylbenzene hydroperoxide, MoO2(acac)2, isopropylbenzene / 1 h / 70 °C 2: H2 / Pd/C / ethanol / 50 °C / 30002.4 Torr View Scheme
参考文献
Balholov; Filadska; Skumov
Russian Journal of General Chemistry, 1997 , vol. 67, # 6 p. 921 - 926
反应条件
pyridinium tribromide in methanol
参考文献
Eglinton,G. et al.
Journal of the Chemical Society [Section] C: Organic, 1969 , p. 474 - 479
反应条件
1: With ozone in dichloromethane T=-78°C; 2: With triphenylphosphine in dichloromethane T=-78 - 20°C; 4 h;
参考文献
Ebran, Jean-Philippe; Hazell, Rita G.; Skrydstrup, Troels
Chemical Communications, 2005 , # 43 p. 5402 - 5404
