3,5-二甲基-1-金刚烷醇合成路线 （共 28 条）
反应条件
1: hydrogen bromide / water / 0.67 h / |Inert atmosphere 2: tri-n-butyl-tin hydride; 2,2'-azo-bisisobutyronitrile / 1 h / 90 °C / |Inert atmosphere View Scheme
参考文献
Kobayashi, Shoji; Kuroda, Hiroyuki; Ohtsuka, Yuta; Kashihara, Takashi; Masuyama, Araki; Watanabe, Kiyoshi
Tetrahedron, 2013 , vol. 69, # 10 p. 2251 - 2259
反应条件
sulfuric acid 72 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Farcasiu, Dan; Marino, Gaye; Rose, Kenneth D.
Journal of Organic Chemistry, 1983 , vol. 48, # 16 p. 2762 - 2765
反应条件
sulfuric acid; boron trifluoride
参考文献
Bott,K.
Chemische Berichte, 1968 , vol. 101, p. 564 - 573
反应条件
1: (i) BF3, (ii) aq. KOH 2: (decarboxylation) View Scheme
参考文献
Landa; Burkhard; Vais
Collection of Czechoslovak Chemical Communications, 1973 , vol. 38, # 10 p. 2947 - 2952
反应条件
(i) H2SO4, (ii) KMnO4, acetone; Multistep reaction;
参考文献
Bott,K.
Justus Liebigs Annalen der Chemie, 1972 , vol. 766, p. 51 - 57
反应条件
1: H2SO4, BF3 2: Br2 3: H2SO4 / 6 h / Heating 4: H2SO4, BF3 5: H2SO4 / 5 h / Heating View Scheme
参考文献
Bott,K.
Chemische Berichte, 1968 , vol. 101, p. 564 - 573
反应条件
trifluoroacetic acid T=90 - 100°C; 10 h;
参考文献
Plakhotnik, V.M.; Kovtun, V.Yu.; Yashunskii, V.G.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 867 - 871
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 5 p. 1001 - 1005
反应条件
1: (i) BF3, (ii) aq. KOH
2: (decarboxylation)
3: LiAlH4
View Scheme
参考文献
Landa; Burkhard; Vais
Collection of Czechoslovak Chemical Communications, 1973 , vol. 38, # 10 p. 2947 - 2952
