丙基 2-乙酰氨基-2-脱氧-beta-D-吡喃葡萄糖苷合成路线 （共 7 条）
反应条件
potassium tert-butylate in methanol
Hydrolysis; 5 h;
参考文献
Kamst, Eric; Zegelaar-Jaarsveld, Korien; Van Der Marel, Gijs A.; Van Boom, Jacques H.; Lugtenberg, Ben J.J.; Spaink, Herman P.
Carbohydrate Research, 1999 , vol. 321, # 3-4 p. 176 - 189
反应条件
hydrogen; palladium dihydroxide in methanol
T=20°C; 1.5 h;
参考文献
Sasaki, Kenji; Nishida, Yoshihiro; Kambara, Mikie; Uzawa, Hirotaka; Takahashi, Tadanobu; Suzuki, Takashi; Suzuki, Yasuo; Kobayashi, Kazukiyo
Bioorganic and Medicinal Chemistry, 2004 , vol. 12, # 6 p. 1367 - 1375
反应条件
1: 35 percent / trimethylsilyl chloride / 0.5 h / 60 - 80 °C
2: 495 mg / H2 / Pd(OH)2/C / methanol / 1.5 h / 20 °C
View Scheme
参考文献
Sasaki, Kenji; Nishida, Yoshihiro; Kambara, Mikie; Uzawa, Hirotaka; Takahashi, Tadanobu; Suzuki, Takashi; Suzuki, Yasuo; Kobayashi, Kazukiyo
Bioorganic and Medicinal Chemistry, 2004 , vol. 12, # 6 p. 1367 - 1375
反应条件
1: H2NNH2*H2O / aq. ethanol / 17 h / Heating
2: pyridine / 20 h / 20 °C
3: 86 percent / potassium tert-butanolate / methanol / 5 h
View Scheme
参考文献
Kamst, Eric; Zegelaar-Jaarsveld, Korien; Van Der Marel, Gijs A.; Van Boom, Jacques H.; Lugtenberg, Ben J.J.; Spaink, Herman P.
Carbohydrate Research, 1999 , vol. 321, # 3-4 p. 176 - 189
反应条件
1: pyridine / 20 h / 20 °C
2: 86 percent / potassium tert-butanolate / methanol / 5 h
View Scheme
参考文献
Kamst, Eric; Zegelaar-Jaarsveld, Korien; Van Der Marel, Gijs A.; Van Boom, Jacques H.; Lugtenberg, Ben J.J.; Spaink, Herman P.
Carbohydrate Research, 1999 , vol. 321, # 3-4 p. 176 - 189
反应条件
1: benzene; mercury (II)-cyanide
2: ammonia; methanol
View Scheme
参考文献
Kuhn; Kirschenlohr
Chemische Berichte, 1953 , vol. 86, p. 1331
参考文献
Zilliken et al.
Archives of Biochemistry, 1955 , vol. 54, p. 398,402
