4-(1-氧代丙氧基)苯甲腈合成路线 （共 9 条）
反应条件
bis(1,5-cyclooctadiene)nickel (0); triphenylphosphine in various solvent(s) T=70°C; 27 h; Product distributionRate constant;
参考文献
Journal of the American Chemical Society, , vol. 102, # 11 p. 3758 - 3764
反应条件
triphenylphosphine in further solvent(s) Kinetics; (N2 or Ar or vac.), EtCOOPh-CN added to Ni(cod)2 and PPh3 (PPh3/Ni = 3)in acetophenone, mixture stirred at 70°C for 27 h; GLC;
参考文献
Journal of the American Chemical Society, , vol. 102, # 11 p. 3758 - 3764
反应条件
carbon monoxide in tetrahydrofuran
(N2 or Ar), complex dissolved in THF, evacuated, excess CO introduced at room temp. for 1 h; IR;
参考文献
Komiya, Sanshiro; Akai, Yasushi; Tanaka, Kohkichi; Yamamoto, Takakazu; Yamamoto, Akio
Organometallics, 1985 , vol. 4, p. 1130 - 1136
反应条件
in water; propionic acid anhydride
参考文献
May and Baker Limited
Patent: US4442115 A1, 1984 ;
反应条件
carbon monoxide in tetrahydrofuran
CO (excess), THF, room temp., 1 h;
参考文献
Komiya, Sanshiro; Akai, Yasushi; Tanaka, Kohkichi; Yamamoto, Takakazu; Yamamoto, Akio
Organometallics, 1985 , vol. 4, p. 1130 - 1136
反应条件
N'-(3-dimethylaminopropyl)-N-ethylcarbodiimide
T=25°C; 0.166667 h;
参考文献
Shelkov, Rimma; Nahmany, Moshe; Melman, Artem
Organic and Biomolecular Chemistry, 2004 , vol. 2, # 3 p. 397 - 401
反应条件
in tetrahydrofuran
(N2 or Ar), at room temp. for 5 h;
参考文献
Komiya, Sanshiro; Akai, Yasushi; Tanaka, Kohkichi; Yamamoto, Takakazu; Yamamoto, Akio
Organometallics, 1985 , vol. 4, p. 1130 - 1136
反应条件
in tetrahydrofuran
Kinetics; (N2 or Ar), at room temp. for 5 h, excess acrylonitrile; UV;
参考文献
Komiya, Sanshiro; Akai, Yasushi; Tanaka, Kohkichi; Yamamoto, Takakazu; Yamamoto, Akio
Organometallics, 1985 , vol. 4, p. 1130 - 1136
反应条件
in tetrahydrofuran
maleic anhydride (3.8 equivs.), THF, room temp., 24 h;
参考文献
Yamamoto, Takakazu; Kohara, Teiji; Yamamoto, Akio
Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 7 p. 2161 - 2168
