norborn-2-ene; oxygen; thiamine diphosphate 0.416667 h; Irradiationphotooxidation of sulfenamides in benzene solution; AIBN reaction; chemical oxidation with endoperoxide; intermediate formation of iminopersulfinic acids; quenching of singlet oxygen, kT; epoxidizing of norbornene; Product distribution;
参考文献
Clennan, Edward L.; Chen, Ming-Fang; Greer, Alexander; Jensen, Frank
Journal of Organic Chemistry, 1998 , vol. 63, # 10 p. 3397 - 3402
catalyst: (Ir(C8H12)Cl)2/(NC5H4C(CH3)3-4)2 in tetrahydrofuran react. indole and benzene with boron compds. in THF in the presence of Ir complex and 4,4'-di-tert-butylbipyridine at 80°C; workup with 3 M aq. sodium acetate;
参考文献
Robbins, Daniel W.; Boebel, Timothy A.; Hartwig, John F.
Journal of the American Chemical Society, 2010 , vol. 132, # 12 p. 4068 - 4069