H
reduction of carbonates of elementes of 2. main group by nascent hydrogen;;
参考文献
Lieben
Monatshefte fuer Chemie, 1895 , vol. 16, p. 211
Monatshefte fuer Chemie, 1897 , vol. 18, p. 582
→
反应条件
water in water
Kinetics; base hydrolysis;
参考文献
Pradhan, G. C.; Nanda, R. K.; Dash, A. C.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1988 , vol. 27, # 10 p. 905 - 906
potassium hydrogencarbonate in water
byproducts: CH4, C2H5OH; Electrochem. Process; potentiostatic electrochemical reduction of CO2 at a Cu electrode (-1.35 to -1.75 V) in KHCO3 aq. solution at 298 K (pCO2 = 104,4-107.4 kPa), further products; gas chromy., HPLC;
