water in water
Electrochem. Process; electroreduction of CO2 at a copper cathode in various aq. solns. at 19°C and ambient pressure; electrolyte: KCl, KClO4, K2SO4, K2HPO4; pH=5.7-7.0; further products: H2, n-PrOH;
参考文献
Hori, Yoshio; Murata, Akira; Takahashi, Ryutaro; Suzuki, Shin
Journal of the Chemical Society, Chemical Communications, 1988 , # 1 p. 17 - 19
OsO5(OH)(3-) in water
Kinetics; mixing of solns. (dimethylamine (2*10**(-4) M), IO4(1-) 4*10**(-3) M, OH(1-) 0.20 M), 298 - 313 K; reaction followed by analytical determination of periodate;
参考文献
Hiremath; Chimatadar; Raju
Journal of the Indian Chemical Society, 1996 , vol. 73, # 6 p. 279 - 281
hydroperoxide anion
P=0.3 Torr; Ambient temperatureabsence of an α-effect in the gas-phase nucleophilic reaction of reagent;
参考文献
DePuy, Charles H.; Della, Ernest W.; Filley, Jonathan; Grabowski, Joseph J.; Bierbaum, Veronica M.
Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2481 - 2482
18OH radical
P=0.3 Torr; Ambient temperatureabsence of an α-effect in the gas-phase nucleophilic reaction of reagent;
参考文献
DePuy, Charles H.; Della, Ernest W.; Filley, Jonathan; Grabowski, Joseph J.; Bierbaum, Veronica M.
Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2481 - 2482
sodium hydroxide; sodium N-bromobenzenesulfonamide; glycine in water
T=40°C; pH=9.94; Kinetics; Further Variations:pH-valuesReagentsSolventsTemperatures;
参考文献
Puttaswamy; Vaz, Nirmala; Made Gowda
International Journal of Chemical Kinetics, 2001 , vol. 33, # 8 p. 480 - 490
sodium hydroxide; sodium N-bromobenzenesulfonamide; glycine in water
T=40°C; pH=9.94; Kinetics; Further Variations:pH-valuesReagentsSolventsTemperatures;
参考文献
Puttaswamy; Vaz, Nirmala; Made Gowda
International Journal of Chemical Kinetics, 2001 , vol. 33, # 8 p. 480 - 490
