potassium chloride; hydroxide in 1,4-dioxane; water
T=25°C; also for the pig liver esterase catalysed hydrolysis; Rate constant;
参考文献
Barton, Patrick; Laws, Andrew P.; Page, Michael I.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1994 , # 9 p. 2021 - 2030
sodium hydroxide; sodium N-bromobenzenesulfonamide; glycine in water
T=40°C; pH=9.94; Kinetics; Further Variations:pH-valuesReagentsSolventsTemperatures;
参考文献
Puttaswamy; Vaz, Nirmala; Made Gowda
International Journal of Chemical Kinetics, 2001 , vol. 33, # 8 p. 480 - 490
in water
Electrolysis; CO2 bubbled through 0.5 M KHCO3 soln., electrolysis at ambient temp. with stirring at constant current; cathode: Cd or In or Sn or Pb or Zn or Ag or Au or Cu or Fe or Ni; GC, ion chromatography, titration;
参考文献
Hori, Yoshio; Kikuchi, Katsuhei; Suzuki, Shin
Chemistry Letters, 1985 , p. 1695 - 1698
phosphate buffer
T=25°C; dissection of nucleophilic and general roles for the reaction of phosphate mono- and dianion; solvent kinetic isotope effect; reaction with D2O at 25 deg C; effect of various pH; Rate constantMechanism;
参考文献
Gill, Manjinder S.; Neverov, Alexei A.; Brown
Journal of Organic Chemistry, 1997 , vol. 62, # 21 p. 7351 - 7357
