289 coulombs; water; [ruthenium(III)(2,2':6',2''-terpyridine)(2,2'-bipyridine)(H2O)]
Ambient temperaturepH 6.8 (0.1 M in (HPO4)2-/(H2PO4)- buffer), at 0.8 V to generate <Ru(trpy)(bpy)O>2+ from <Ru(trpy)(bpy)H2O>2+;
参考文献
Thompson, Mark S.; Giovani, Wagner F. De; Moyer, Bruce A.; Meyer, Thomas J.
Journal of Organic Chemistry, 1984 , vol. 49, # 25 p. 4972 - 4977
potassium chloride; hydroxide in 1,4-dioxane; water
T=25°C; also for the pig liver esterase catalysed hydrolysis; Rate constant;
参考文献
Barton, Patrick; Laws, Andrew P.; Page, Michael I.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1994 , # 9 p. 2021 - 2030
in sulfuric acid; acetic acid
Kinetics; byproducts: [H4(tetraphenylporphyrin(o-NO2)4](2+); dissociation in 6 and 7 M H2SO4; reaction mechanism discussed;; not isolated; only in soln.; detection of macroligand by UV spectroscopy;;
参考文献
Lomova, T. N.; Shormanova, L. P.; Berezin, B. D.; Antonova, S.V.
Russian Journal of Physical Chemistry, 1986 , vol. 60, # 3 p. 350 - 352
Zhurnal Fizicheskoi Khimii, 1986 , vol. 60, p. 590 - 593
