2-氟-2-甲基-1-苯基-1-丙酮合成路线 （共 8 条）
反应条件
nonafluoro-n-butanesulfonyl fluoride; triethylamine tris(hydrogen fluoride); triethylamine in acetonitrile
T=95°C; 9 h;
参考文献
Yin, Jingjun; Zarkowsky, Devin S.; Thomas, David W.; Zhao, Matthew M.; Huffman, Mark A.
Organic Letters, 2004 , vol. 6, # 9 p. 1465 - 1468
反应条件
hydrogen fluoride; accufluorTM in water; acetonitrile
T=80°C; 12 h;
参考文献
Stavber, Stojan; Zupan, Marko
Tetrahedron Letters, 1996 , vol. 37, # 20 p. 3591 - 3594
反应条件
1: With iodotoluene difluoride; boron trifluoride diethyl etherate in dichloromethane
T=-78°C; 2 h;
2: With triethylamine tris(hydrogen fluoride) in dichloromethane
1 h;
参考文献
Sato, Saeko; Yoshida, Masanori; Hara, Shoji
Synthesis, 2005 , # 15 art. no. F18704SS, p. 2602 - 2605
反应条件
boron trifluoride diethyl etherate in benzene
T=40°C; 18 h;
参考文献
Flamming, R.; Lacombe, S.; Laurent, A.; Maquestiau, A.; Marquet, B.; Novkova, S.
Tetrahedron, 1986 , vol. 42, # 1 p. 315 - 328
反应条件
triethylamine tris(hydrogen fluoride); triethylamine in acetonitrile
T=80°C; 20 h;
参考文献
Giudicelli; Pica; Veyron
Tetrahedron Letters, 1990 , vol. 31, # 45 p. 6527 - 6530
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene; Xtalfluor-E® in dichloromethane
T=20°C; 24 h; Inert atmosphere;
参考文献
Lheureux, Alexandre; Beaulieu, Francis; Bennett, Christopher; Bill, David R.; Clayton, Simon; Laflamme, Franois; Mirmehrabi, Mahmoud; Tadayon, Sam; Tovell, David; Couturier, Michel
Journal of Organic Chemistry, 2010 , vol. 75, # 10 p. 3401 - 3411
反应条件
triethylamine tris(hydrogen fluoride) in acetonitrile
anodic oxidation;
参考文献
Laurent, Eliane; Tardivel, Robert; Thiebault, Hugues
Tetrahedron Letters, 1983 , vol. 24, # 9 p. 903 - 906
反应条件
hydrogen fluoride; triethylamine in acetonitrile
anodic oxidation on graphite, potentiostatic, U = +1.9 V vs. Ag/Ag(+), charge: 2.6 F/mol; Yield given. Yields of byproduct given;
参考文献
Laurent, E.; Marquet, B; Tardivel, R.; Thiebault, H.
Bulletin de la Societe Chimique de France, 1986 , # 6 p. 955 - 964
