8-丁氧基-2,6-二甲基辛-2-烯合成路线 （共 3 条）
反应条件
in tetrahydrofuran; hexane
T=-78 - 20°C; 4 h; Inert atmosphere;
参考文献
Willand-Charnley, Rachel; Puffer, Benjamin W.; Dussault, Patrick H.
Journal of the American Chemical Society, 2014 , vol. 136, # 16 p. 5821 - 5823
反应条件
1.1: cesium hydroxide monohydrate / N,N-dimethyl-formamide / 0.5 h / 0 °C / |Inert atmosphere
1.2: 5 h / 0 - 20 °C / |Inert atmosphere
2.1: tetrahydrofuran; hexane / 4 h / -78 - 20 °C / |Inert atmosphere
View Scheme
参考文献
Willand-Charnley, Rachel; Puffer, Benjamin W.; Dussault, Patrick H.
Journal of the American Chemical Society, 2014 , vol. 136, # 16 p. 5821 - 5823
反应条件
1.1: triethylamine / dichloromethane / 16 h / 0 - 20 °C / |Inert atmosphere
2.1: cesium hydroxide monohydrate / N,N-dimethyl-formamide / 0.5 h / 0 °C / |Inert atmosphere
2.2: 5 h / 0 - 20 °C / |Inert atmosphere
3.1: tetrahydrofuran; hexane / 4 h / -78 - 20 °C / |Inert atmosphere
View Scheme
参考文献
Willand-Charnley, Rachel; Puffer, Benjamin W.; Dussault, Patrick H.
Journal of the American Chemical Society, 2014 , vol. 136, # 16 p. 5821 - 5823
