5,5-二甲基-1-己烯合成路线 （共 39 条）
反应条件
1.) CuCN
1) THF, pentane, -78 to -10 deg C; 2) THF, pentane, -78 to -10 deg C, 3 h; Yield given. Multistep reaction;
参考文献
Hendel, Robert A.; Nomura, Eisaku; Janout, Vaclav; Regen, Steven L.
Journal of the American Chemical Society, 1997 , vol. 119, # 29 p. 6909 - 6918
反应条件
1: 1.) n-butyllithium, 2.) hexamethylphosphoric triamide (HMPA) / 1.) hexane, diethyl ether, -70 deg C, 25 min, 2.) hexane, diethyl, RT, 2 h
2: 84 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 0.67 h / Heating
View Scheme
参考文献
Hsiao, C.-N.; Shechter, H.
Journal of Organic Chemistry, 1988 , vol. 53, # 12 p. 2688 - 2699
反应条件
dicyclo-hexylphosphine in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=24°C; 4 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Ashby, E.C.; Argyropoulos, J.N.
Tetrahedron Letters, 1984 , vol. 25, # 1 p. 7 - 10
反应条件
NaSnMe3 in tetrahydrofuran
T=0°C; 8 h;
参考文献
Ashby, E. C.; Deshpande, Abhay K.
Journal of Organic Chemistry, 1994 , vol. 59, # 24 p. 7358 - 7366
反应条件
lithium triethylborohydride in tetrahydrofuran
T=24°C; 24 h;
参考文献
Ashby, Eugene C.; DePriest, Robert N.; Goel, Anil B.
Tetrahedron Letters, 1981 , vol. 22, # 19 p. 1763 - 1766
反应条件
triphenyl phosphite; hydrogen; [rhodium(I)(carbonyl)2(acetylacetonate)]
1.) benzene, 60 degC, 50-100 atm; Yield given. Multistep reaction;
参考文献
Nozaki, Kyoko; Nanno, Tetsuo; Takaya, Hidemasa
Journal of Organometallic Chemistry, 1997 , vol. 527, # 1-2 p. 103 - 108
反应条件
lithium aluminium tetrahydride in tetrahydrofuran
T=24°C; 480 h;
参考文献
Ashby, Eugene C.; DePriest, Robert N.; Goel, Anil B.
Tetrahedron Letters, 1981 , vol. 22, # 19 p. 1763 - 1766
反应条件
dicyclo-hexylphosphine in N,N,N',N',N'',N''-hexamethylphosphoric triamide
1 h; Further byproducts given;
参考文献
Ashby, E. C.; Bae, Dong-Hak; Park, Won-Suh; Depriest, Robert N.; Su, Wei-Yang
Tetrahedron Letters, 1984 , vol. 25, # 45 p. 5107 - 5110
反应条件
lithium tert-butylate; dicyclo-hexylphosphine in N,N,N',N',N'',N''-hexamethylphosphoric triamide
1 h;
参考文献
Ashby, E. C.; Bae, Dong-Hak; Park, Won-Suh; Depriest, Robert N.; Su, Wei-Yang
Tetrahedron Letters, 1984 , vol. 25, # 45 p. 5107 - 5110
反应条件
lithium tert-butylate in N,N,N',N',N'',N''-hexamethylphosphoric triamide
336 h;
参考文献
Ashby, E. C.; Bae, Dong-Hak; Park, Won-Suh; Depriest, Robert N.; Su, Wei-Yang
Tetrahedron Letters, 1984 , vol. 25, # 45 p. 5107 - 5110
