(1S)-(-)-10-巯基异冰片合成路线 （共 8 条）
反应条件
lithium aluminium tetrahydride in diethyl ether 1.) RT, 2.) reflux;
参考文献
Journal of Organic Chemistry, , vol. 51, # 9 p. 1457 - 1466
反应条件
samarium diiodide in tetrahydrofuran; tert-butyl alcohol 0.166667 h; Ambient temperature; Yields of byproduct given;
参考文献
Arai, Yoshitsugu; Hayashi, Kazuya; Matsui, Makoto; Koizumi, Toru; Shiro, Motoo; Kuriyama, Kaoru
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 7 p. 1709 - 1716
反应条件
samarium diiodide in tetrahydrofuran; tert-butyl alcohol 0.166667 h; Ambient temperature; Yields of byproduct given;
参考文献
Arai, Yoshitsugu; Matsui, Makoto; Koizumi, Toru
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 4 p. 1233 - 1234
反应条件
1: 61 percent / DIBAL / toluene / 12 h / Ambient temperature 2: SmI2, t-BuOH / tetrahydrofuran / 0.17 h View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 7 p. 1709 - 1716
反应条件
1: 87 percent / PCl5 2: 60 percent / LAH / diethyl ether / Heating View Scheme
参考文献
Journal of Chemical Research, Miniprint, , # 10 p. 1056 - 1069
反应条件
1: ZnCl2 / -40 to -20 deg C, 3h 2: i-Bu2AlH / toluene / -78 °C 3: SmI2 / tetrahydrofuran; 2-methyl-propan-2-ol / 0.17 h / Ambient temperature View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 4 p. 1233 - 1234
反应条件
1: i-Bu2AlH / toluene 2: SmI2 / tetrahydrofuran; 2-methyl-propan-2-ol / 0.17 h / Ambient temperature View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 4 p. 1233 - 1234
反应条件
lithium aluminium tetrahydride a.) -78 deg C, b.) reflux;
参考文献
Journal of Organic Chemistry, , vol. 56, # 15 p. 4760 - 4766
