phenyl silane; oxygen; bis(dipivaloylmethanato)manganese(II) in isopropyl alcohol T=0°C; P=760 Torr; 3 h; effect of other Mn(II) complexes and solvents; other substrates; Mechanism;

Grubb's 2nd generation catalyst; triethylsilane in dichloromethane T=150°C; 0.5 h; Microwave irradiation; chemoselective reaction;

(chloromethyl)silane in dichloromethane 4 h; Ambient temperature;

1: With bis(.eta.(2)-ethylene)(2,4,-pentanedionato)rhodium; (S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl in 1,4-dioxane; water T=100°C; Arylation; 16 h; 2: With hydrogen; palladium on activated charcoal in ethanol T=20°C; Catalytic hydrogenation; P=1140.08 Torr; 3 h; Saponification; Further stages.;

sodium hydride in diethyl ether; dimethyl sulfoxide 0.5 h; Ambient temperature;

1: 68 percent / NaH / diethyl ether; dimethylsulfoxide / 0.5 h / Ambient temperature 2: 1.) HCl, 2.) H2O / 1.) Et2O, from 0 deg C to 20 deg C, 1 h, 2.) MeOH, 70 deg C, 20 min View Scheme

n-butyllithium; Imes; lithium chloride in toluene T=20°C; 28 h; Inert atmosphere;