氯代(环戊二烯基)[双(二苯基膦)甲烷]钌(II)合成路线 （共 3 条）
反应条件
in benzene Ru-complex and Rh-complex were reacted in stirring benzene for 90 min under N2; solvent was removed in vac., fractional crystd. from CHCl3-light petroleum;
参考文献
Bruce, Michael I.; Humphrey, Mark G.; Patrick, Jennifer M.; White, Allan H.
Australian Journal of Chemistry, 1983 , vol. 36, # 10 p. 2065 - 2072
反应条件
in dichloromethane 12 h; Inert atmosphere;
参考文献
Perekalin, Dmitry S.; Karslyan, Eduard E.; Trifonova, Evgeniya A.; Konovalov, Andrew I.; Loskutova, Natalia L.; Nelyubina, Yulia V.; Kudinov, Alexander R.
European Journal of Inorganic Chemistry, 2013 , # 4 p. 481 - 493
反应条件
in 1,2-dichloro-ethane; benzene Ru-complex was placed in flask under 1 atm of H2, dichloroethane and benzene were added, stirred at room temp. for 15 min, W-complex was added, stirred at room temp. for 24 h; evapd. under reduced pressure, trapped in H2SO4, aq. KOH was added, distilled into H2SO4;
参考文献
Inorganic Chemistry, , vol. 39, # 26 p. 5946 - 5957
