1-硝基-9-氧代-9,10-二氢-4-吖啶羧酸合成路线 (共 8 条)
反应条件
1: 61 percent / copper(II) acetate / dimethylformamide / 12 h / 100 °C
2: polyphosphoric ethyl ester / CHCl3 / 1 h / Heating
3: aq. NaOH / ethanol / 0.17 h / Heating
View Scheme
参考文献
Rewcastle, Gordon W.; Denny, William A.
Synthesis, 1985 , # 2 p. 220 - 222
反应条件
1: 61 percent / copper(II) acetate / dimethylformamide / 12 h / 100 °C
2: polyphosphoric ethyl ester / CHCl3 / 1 h / Heating
3: aq. NaOH / ethanol / 0.17 h / Heating
View Scheme
参考文献
Rewcastle, Gordon W.; Denny, William A.
Synthesis, 1985 , # 2 p. 220 - 222
反应条件
phosphorus pentachloride; nitrobenzene
参考文献
Matsumura
Journal of the American Chemical Society, 1938 , vol. 60, p. 593
反应条件
1: potassium carbonate; copper; amyl alcohol
2: PCl5; nitrobenzene; AlCl3
View Scheme
参考文献
Matsumura
Journal of the American Chemical Society, 1938 , vol. 60, p. 593
反应条件
1: potassium carbonate; copper; amyl alcohol
2: PCl5; nitrobenzene; AlCl3
View Scheme
参考文献
Matsumura
Journal of the American Chemical Society, 1938 , vol. 60, p. 593
反应条件
water; trichlorophosphate
1.) reflux, 1 h, 2.) 100 deg C, 10 min; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Stewart, Georgina M.; Rewcastle, Gordon W.; Denny, William A.
Australian Journal of Chemistry, 1984 , vol. 37, # 9 p. 1939 - 1950
反应条件
1: SnCl2; concentrated aqueous HCl; acetic acid
2: acetic acid; aqueous HCl
View Scheme
参考文献
Matsumura
Journal of the American Chemical Society, 1938 , vol. 60, p. 593
反应条件
hydrogenchloride; acetic acid; tin(ll) chloride
参考文献
Matsumura
Journal of the American Chemical Society, 1938 , vol. 60, p. 593