(4-(萘-1-基(苯基)氨基)苯基)硼酸合成路线 （共 4 条）
反应条件
1: With n-butyllithium in tetrahydrofuran
T=-78°C;
2: With boric acid trimethyl ester in tetrahydrofuran
T=-78 - 20°C;
3: With hydrogenchloride in tetrahydrofuran; water
参考文献
DOOSAN CORPORATION
Patent: WO2009/82157 A2, 2009 ;
Location in patent: Page/Page column 27-28 ;
反应条件
1: 4-bromo-1-iodobenzene; 1-(N-phenylamino)-naphthalene With copper(l) iodide; sodium t-butanolate; N-methyl-2-(methylamino)ethylamine in toluene
T=110°C; 8 h; Inert atmosphere;
2: With n-butyllithium in anhydrous xylene; hexane
T=-30°C; 1 h; Inert atmosphere;
3: tri-isopropoxy-borane Further stages;
参考文献
Idemitsu Kosan Co., Ltd.; KATO, Tomoki; ITO, Mitsunori; INOUE, Tetsuya; OGIWARA, Toshinari; HIBINO, Kumiko
Patent: EP2589596 A1, 2013 ;
Location in patent: Paragraph 0103; 0104 ;
反应条件
1: N-(4-bromophenyl)-N-phenylnaphthalen-1-amine With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 1 h;
2: tri-isopropoxy-borane in tetrahydrofuran; hexane
T=-78 - 20°C;
参考文献
Jia, Wen Li; Moran, Mark J.; Yuan, Yan-Yan; Lu, Zheng Hong; Wang, Suning
Journal of Materials Chemistry, 2005 , vol. 15, # 32 p. 3326 - 3333
反应条件
1: N-(4-bromophenyl)-N-phenylnaphthalen-1-amine With n-butyllithium in hexane; xylene
T=-30°C; 1 h;
2: tri-isopropoxy-borane in hexane; xylene
T=-70 - 20°C; 1 h;
3: water With hydrogenchloride in hexane; xylene
参考文献
IDEMITSU KOSAN CO., LTD.
Patent: WO2006/73054 A1, 2006 ;
Location in patent: Page/Page column 72-73 ;
