pyridine in diethyl ether; acetic acid 1 h;

1: 89 percent / NEt3 / toluene / 20 h / Heating 2: 86 percent / LiAlH4 / diethyl ether / 10 h / Heating 3: 47 percent / 70 °C 4: neat (no solvent) / 134.9 °C / lgA, EA, ΔH(excit.), ΔS(excit.), ΔG(excit.), ΔrH View Scheme

1: 1) Mg / 1) Et2O, 2a) pettrol ether, 14h, RT, 2b) 8h, reflux 2: 89 percent / NEt3 / toluene / 20 h / Heating 3: 86 percent / LiAlH4 / diethyl ether / 10 h / Heating 4: 47 percent / 70 °C 5: neat (no solvent) / 134.9 °C / lgA, EA, ΔH(excit.), ΔS(excit.), ΔG(excit.), ΔrH View Scheme

1: 86 percent / LiAlH4 / diethyl ether / 10 h / Heating 2: 47 percent / 70 °C 3: neat (no solvent) / 134.9 °C / lgA, EA, ΔH(excit.), ΔS(excit.), ΔG(excit.), ΔrH View Scheme

1: 47 percent / 70 °C 2: neat (no solvent) / 134.9 °C / lgA, EA, ΔH(excit.), ΔS(excit.), ΔG(excit.), ΔrH View Scheme

T=135°C; 65 h;

暂无反应条件数据