7,12-二甲基苯并(a)蒽-3,4-二醇合成路线 （共 6 条）
反应条件
lithium aluminium tetrahydride in diethyl ether
参考文献
Sukumaran, K.B.; Harvey, Ronald G.
Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4407 - 4413
反应条件
1: 0.10 g / o-iodoxybenzoic acid / dimethylformamide / 0.17 h
2: NaBH4 / dimethylformamide
View Scheme
参考文献
Harvey, Ronald G.; Dai, Qing; Ran, Chongzhao; Penning, Trevor M.
Journal of Organic Chemistry, 2004 , vol. 69, # 6 p. 2024 - 2032
反应条件
1: BBr3 / CH2Cl2 / 20 °C
2: 0.10 g / o-iodoxybenzoic acid / dimethylformamide / 0.17 h
3: NaBH4 / dimethylformamide
View Scheme
参考文献
Harvey, Ronald G.; Dai, Qing; Ran, Chongzhao; Penning, Trevor M.
Journal of Organic Chemistry, 2004 , vol. 69, # 6 p. 2024 - 2032
反应条件
sodium tetrahydroborate in N,N-dimethyl-formamide
参考文献
Harvey, Ronald G.; Dai, Qing; Ran, Chongzhao; Penning, Trevor M.
Journal of Organic Chemistry, 2004 , vol. 69, # 6 p. 2024 - 2032
反应条件
1: 1.) NaH; 2.) phenylseleninic anhydride
2: LiAlH4 / diethyl ether
View Scheme
参考文献
Sukumaran, K.B.; Harvey, Ronald G.
Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4407 - 4413
反应条件
1: 95 percent / NaBH4 / dimethylsulfoxide / 5 h / Ambient temperature
2: 95 percent / lithium thiomethoxide / dimethylformamide / 4 h / Heating
3: 81 percent / potassium dihydrogen phosphate, <(KSO3)2NO> / methanol; H2O / 16 h / 35 °C
4: LiAlH4 / diethyl ether
View Scheme
参考文献
Sukumaran, K.B.; Harvey, Ronald G.
Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4407 - 4413
