甲基 3-O-alpha-D-甘露糖基-alpha-D-吡喃甘露糖苷合成路线 （共 28 条）
反应条件
hydrogen; palladium on activated charcoal in ethanol; acetic acid P=2625.2 Torr;
参考文献
Madiyalakan, Ragupathy; Chowdhary, Manjit S.; Rana, Surjit S.; Matta, Khushi L.
Carbohydrate Research, 1986 , vol. 152, p. 183 - 194
反应条件
hydrogen; palladium on activated charcoal in ethanol 1) 45 deg C, 3 h; 2) 25 deg C, 16 h;
参考文献
Ogawa, Tomoya; Sasajima, Kikuo
Carbohydrate Research, 1981 , vol. 93, p. 53 - 66
反应条件
sodium methylate in methanol 1 h;
参考文献
Chowdhary, Manjit S.; Jain, Rakesh K.; Rana, Surjit S.; Matta, Khushi L.
Carbohydrate Research, 1986 , vol. 152, p. 323 - 328
反应条件
1: 81 percent / 4 Angstroem molecular sieves, silver triflate / CH2Cl2; toluene / 0.67 h / -40 °C 2: HOAc, H2 / Pd-C / ethanol 3: 79 percent / NaOMe / Ambient temperature View Scheme
参考文献
Journal of Carbohydrate Chemistry, , vol. 17, # 3 p. 417 - 437
反应条件
1: 55 percent / TFA; Et3SiH / CH2Cl2 / 0.75 h / 0 °C 2: 93 percent / pyridine; 3 Angstroem molecular sieves / CH2Cl2 / 0.42 h / -40 °C 3: 99 percent / H2 / Pd black / ethanol; ethyl acetate / 16.75 h 4: 93 percent / DMAP; DCC / CH2Cl2 / 5.33 h / 20 °C 5: 79 percent / H2 / Pd / ethanol / 0.5 h / 20 °C View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 14, # 9 p. 1201 - 1210
反应条件
1: 37 percent / camphorsulfonic acid / dimethylformamide / 32.75 h / 60 °C / 195.02 Torr 2: 55 percent / TFA; Et3SiH / CH2Cl2 / 0.75 h / 0 °C 3: 93 percent / pyridine; 3 Angstroem molecular sieves / CH2Cl2 / 0.42 h / -40 °C 4: 99 percent / H2 / Pd black / ethanol; ethyl acetate / 16.75 h 5: 93 percent / DMAP; DCC / CH2Cl2 / 5.33 h / 20 °C 6: 79 percent / H2 / Pd / ethanol / 0.5 h / 20 °C View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 14, # 9 p. 1201 - 1210
反应条件
1: 93 percent / pyridine; 3 Angstroem molecular sieves / CH2Cl2 / 0.42 h / -40 °C 2: 99 percent / H2 / Pd black / ethanol; ethyl acetate / 16.75 h 3: 93 percent / DMAP; DCC / CH2Cl2 / 5.33 h / 20 °C 4: 79 percent / H2 / Pd / ethanol / 0.5 h / 20 °C View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 14, # 9 p. 1201 - 1210
反应条件
1: 93 percent / DMAP; DCC / CH2Cl2 / 5.33 h / 20 °C 2: 79 percent / H2 / Pd / ethanol / 0.5 h / 20 °C View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 14, # 9 p. 1201 - 1210
反应条件
1: 99 percent / H2 / Pd black / ethanol; ethyl acetate / 16.75 h 2: 93 percent / DMAP; DCC / CH2Cl2 / 5.33 h / 20 °C 3: 79 percent / H2 / Pd / ethanol / 0.5 h / 20 °C View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 14, # 9 p. 1201 - 1210
反应条件
1: 79 percent / H2 / Pd / ethanol / 0.5 h / 20 °C View Scheme
参考文献
Tetrahedron Asymmetry, , vol. 14, # 9 p. 1201 - 1210
