2-[2-(2-苯氧基乙氧基)乙氧基]-乙醇合成路线 （共 10 条）
反应条件
1: 48 percent / phosphorous tribromide / pyridine / 0 - 50 °C 2: 72 percent / 1.) potassium hydroxide / H2O / 1.) 115 deg C, 1h; 2.) 120 deg C, 1h View Scheme
参考文献
Jursic, Branko
Tetrahedron, 1988 , vol. 44, # 5 p. 1553 - 1558
反应条件
potassium carbonate in benzene
73 h; Heating;
参考文献
Kimura, Masaru; Kajita, Kazushige; Onoda, Naoyuki; Morosawa, Shiro
Journal of Organic Chemistry, 1990 , vol. 55, # 16 p. 4887 - 4892
反应条件
potassium hydroxide in water
1.) 115 deg C, 1h; 2.) 120 deg C, 1h;
参考文献
Jursic, Branko
Tetrahedron, 1988 , vol. 44, # 5 p. 1553 - 1558
反应条件
sodium hydroxide
T=160°C; 5.00333 - 5.01167 h; Product distribution / selectivity;
参考文献
DOW GLOBAL TECHNOLOGIES INC.
Patent: WO2009/76275 A1, 2009 ;
Location in patent: Page/Page column 13-15 ;
反应条件
potassium carbonate in N,N-dimethyl-formamide
T=50°C;
参考文献
Mertens, Ingrid J. A.; Wegh, Rene; Jenneskens, Leonardus W.; Vlietstra, Edward J.; Van Der Kerk-van Hoof, Anca; Zwikker, Jan W.; Cleij, Thomas J.; Smeets, Wilberth J. J.; Veldman, Nora; Spek, Anthony L.
Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 3 p. 725 - 736
反应条件
1: 62 percent / phosphorous tribromide / pyridine / 0 - 50 °C
2: 67 percent / 1.) potassium hydroxide / H2O / 1.) 115 deg C, 1h; 2.) 120 deg C, 1h
View Scheme
参考文献
Jursic, Branko
Tetrahedron, 1988 , vol. 44, # 5 p. 1553 - 1558
反应条件
trifluoroacetic acid
T=160°C; 5.00333 - 5.01167 h; Product distribution / selectivity;
参考文献
DOW GLOBAL TECHNOLOGIES INC.
Patent: WO2009/76275 A1, 2009 ;
Location in patent: Page/Page column 13-15 ;
参考文献
Shukis; Tallman
Journal of the American Chemical Society, 1944 , vol. 66, p. 1462
反应条件
phenolated sodium
T=200°C;
参考文献
Miller et al.
Journal of the Chemical Society, 1950 , p. 3623,3628
反应条件
T=100°C; Einleiten von Aethylenoxyd;
参考文献
I.G. Farbenind.
Patent: DE519730 , 1925 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 17, p. 561
