hydrogenchloride; water in tetrahydrofuran T=0 - 4°C; 18 h; Product distribution / selectivity;

sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine in toluene T=0 - 20°C; 4.5 h;

dicarbonylacetylacetonato rhodium (I); C76H88O12P2Si4; hydrogen; Na[B(3,5-(CF3)2C6H3)4] in tetrahydrofuran; toluene T=40°C; P=7500.75 Torr; 18 h; GloveboxInert atmosphereAutoclave; Reagent/catalyst; enantioselective reaction;

Rh(acac)(CO)2; 3,3',5,5'-tetra(2,4-difluorophenyl)-2,2',6,6'-tetra((di-1-pyrrolylphosphino)oxy)-1,1'-biphenyl; hydrogen in toluene T=120°C; P=3800.26 Torr; 2 h; Autoclave; regioselective reaction;

bis[(S,S,S)-DiazaPhos-SPE]; [rhodium(I)(carbonyl)2(acetylacetonate)]; hydrogen in tetrahydrofuran; toluene T=40°C; P=8000.32 Torr; 4 h; optical yield given as percent eeenantioselective reaction;

[Rh(acac)2(CO)2]; C50H44Cl4N4O4P2; hydrogen in toluene T=60°C; P=15001.5 Torr; 20 h; Inert atmosphereAutoclave; enantioselective reaction;