1: KOH / ethanol; H2O / 18 h / 20 °C 2: 0.24 g / K2CO3 / acetone / 12 h / Heating 3: 85 percent / Na2CO3; LiCl / [Pd(PPh3)4] / acetonitrile / 48 h / Heating View Scheme

1: 90 percent / BF3*Et2O / CH2Cl2 / 0.42 h / -78 °C 2: 65 percent / DDQ / benzene / 24 h / Heating 3: KOH / ethanol; H2O / 18 h / 20 °C 4: 0.24 g / K2CO3 / acetone / 12 h / Heating 5: 85 percent / Na2CO3; LiCl / [Pd(PPh3)4] / acetonitrile / 48 h / Heating View Scheme

144 h; Ambient temperature;

1: 90 percent / DIBAH / diethyl ether; hexane / 3.5 h / -78 °C 2: MnO2 / CCl4 / 6 h / Ambient temperature View Scheme

1: K2CO3 / acetone / 7 h / Heating 2: 90 percent / DIBAH / diethyl ether; hexane / 3.5 h / -78 °C 3: MnO2 / CCl4 / 6 h / Ambient temperature View Scheme

1: N-bromosuccinmide / N,N-dimethyl-formamide / 0.5 h / 20 °C / Inert atmosphere 2: triethylamine / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere 3: tetrakis(triphenylphosphine) palladium(0); tri-n-butyl-tin hydride / N,N-dimethyl-formamide / 0.75 h / 100 °C / Inert atmosphere 4: methanol; copper(l) iodide / N,N-dimethyl-formamide / 5 h / 120 °C / Inert atmosphere View Scheme

1: triethylamine / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere 2: tetrakis(triphenylphosphine) palladium(0); tri-n-butyl-tin hydride / N,N-dimethyl-formamide / 0.75 h / 100 °C / Inert atmosphere 3: methanol; copper(l) iodide / N,N-dimethyl-formamide / 5 h / 120 °C / Inert atmosphere View Scheme

1: tetrakis(triphenylphosphine) palladium(0); tri-n-butyl-tin hydride / N,N-dimethyl-formamide / 0.75 h / 100 °C / Inert atmosphere 2: methanol; copper(l) iodide / N,N-dimethyl-formamide / 5 h / 120 °C / Inert atmosphere View Scheme

1.1: trichlorophosphate / 10 - 20 °C / Inert atmosphere 1.2: 20 - 35 °C / Inert atmosphere 1.3: 20 - 30 °C / Inert atmosphere 2.1: N-bromosuccinmide / N,N-dimethyl-formamide / 0.5 h / 20 °C / Inert atmosphere 3.1: triethylamine / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere 4.1: tetrakis(triphenylphosphine) palladium(0); tri-n-butyl-tin hydride / N,N-dimethyl-formamide / 0.75 h / 100 °C / Inert atmosphere 5.1: methanol; copper(l) iodide / N,N-dimethyl-formamide / 5 h / 120 °C / Inert atmosphere View Scheme

1.1: pyridine / dichloromethane / 0.25 h / 20 °C 1.2: 1 h / -20 °C 2.1: caesium carbonate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl / toluene / 12 h / 96 °C 3.1: potassium carbonate; palladium diacetate; 2,2,2-trimethylacetic acid / 12 h / 115 °C View Scheme