(5S)-5,6-二氢-6,6-二甲基-5-苯基-2H-1,4-恶嗪-2-酮合成路线 （共 5 条）
反应条件
lead(IV) acetate in acetonitrile
T=20°C; 2 h;
参考文献
Tohma, Shigemitsu; Rikimaru, Kentaro; Endo, Atsushi; Shimamoto, Keiko; Kan, Toshiyuki; Fukuyama, Tohru
Synthesis, 2004 , # 6 p. 909 - 917
反应条件
1.1: 88 percent / acetonitrile / 0.5 h / 20 °C
2.1: tetrahydrofuran / 2 h / 20 °C
3.1: SOCl2; MeOH / 1 h / 20 °C
4.1: propylene oxide / acetonitrile / 4 h / 80 °C
4.2: 75 percent / toluene / 15 h / Heating
5.1: 7 percent / Pb(OAc)4 / acetonitrile / 2 h / 20 °C
View Scheme
参考文献
Tohma, Shigemitsu; Rikimaru, Kentaro; Endo, Atsushi; Shimamoto, Keiko; Kan, Toshiyuki; Fukuyama, Tohru
Synthesis, 2004 , # 6 p. 909 - 917
反应条件
1.1: tetrahydrofuran / 2 h / 20 °C
2.1: SOCl2; MeOH / 1 h / 20 °C
3.1: propylene oxide / acetonitrile / 4 h / 80 °C
3.2: 75 percent / toluene / 15 h / Heating
4.1: 7 percent / Pb(OAc)4 / acetonitrile / 2 h / 20 °C
View Scheme
参考文献
Tohma, Shigemitsu; Rikimaru, Kentaro; Endo, Atsushi; Shimamoto, Keiko; Kan, Toshiyuki; Fukuyama, Tohru
Synthesis, 2004 , # 6 p. 909 - 917
反应条件
1.1: propylene oxide / acetonitrile / 4 h / 80 °C
1.2: 75 percent / toluene / 15 h / Heating
2.1: 7 percent / Pb(OAc)4 / acetonitrile / 2 h / 20 °C
View Scheme
参考文献
Tohma, Shigemitsu; Rikimaru, Kentaro; Endo, Atsushi; Shimamoto, Keiko; Kan, Toshiyuki; Fukuyama, Tohru
Synthesis, 2004 , # 6 p. 909 - 917
反应条件
1.1: SOCl2; MeOH / 1 h / 20 °C
2.1: propylene oxide / acetonitrile / 4 h / 80 °C
2.2: 75 percent / toluene / 15 h / Heating
3.1: 7 percent / Pb(OAc)4 / acetonitrile / 2 h / 20 °C
View Scheme
参考文献
Tohma, Shigemitsu; Rikimaru, Kentaro; Endo, Atsushi; Shimamoto, Keiko; Kan, Toshiyuki; Fukuyama, Tohru
Synthesis, 2004 , # 6 p. 909 - 917
