二氟甲基亚基-(三氟甲基)膦合成路线 （共 18 条）
反应条件
(CH3)3N
in presence of 1percent (CH3)3N;
参考文献
Ansari, S.; Grobe, J.; Schmid, P.
Journal of Fluorine Chemistry, 1972 , vol. 2, p. 281 - 297
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Gmelin Handbook: F: PerFHalOrg.3, 1.2, page 14 - 30
反应条件
byproducts: C6H6; intermediate detected by 19F-NMR spectroscopy;
参考文献
Ansari, S.; Grobe, J.; Schmid, P.
Journal of Fluorine Chemistry, 1972 , vol. 2, p. 281 - 297
View citing articles Show Details
Gmelin Handbook: F: PerFHalOrg.3, 1.2, page 14 - 30
反应条件
T=460°C; P=0.001 Torr; 1.2 h; other temperature; Product distributionThermodynamic data;
参考文献
Binnewies, Michael; Grobe, Joseph; Van, Duc Le
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1985 , vol. 40, # 7 p. 927 - 933
反应条件
T=640°C; P=0.001 Torr; 3.2 h; Product distribution;
参考文献
Binnewies, Michael; Grobe, Joseph; Van, Duc Le
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1985 , vol. 40, # 7 p. 927 - 933
反应条件
immediate decompn. of intermediate;
参考文献
Ansari, S.; Grobe, J.; Schmid, P.
Journal of Fluorine Chemistry, 1972 , vol. 2, p. 281 - 297
View citing articles Show Details
Gmelin Handbook: F: PerFHalOrg.3, 1.2, page 14 - 30
反应条件
T=600°C; P=0.001 Torr; 2.3 h; other temperature; Product distribution;
参考文献
Binnewies, Michael; Grobe, Joseph; Van, Duc Le
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1985 , vol. 40, # 7 p. 927 - 933
反应条件
T=770°C; Product distribution;
参考文献
Binnewies, Michael; Grobe, Joseph; Van, Duc Le
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1985 , vol. 40, # 7 p. 927 - 933
反应条件
water in deuterated toluene
T=70°C; 24 h; other temperature: room temp.; other reagents: aq. H2SO4 (pH=3), aq. KOH (pH=10); Product distribution;
参考文献
Grobe, Joseph; Van, Duc Le; Nientiedt, Juergen
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1986 , vol. 41, # 2 p. 149 - 161
