2,7-二溴-9-辛基-9h-咔唑合成路线 （共 4 条）
反应条件
potassium carbonate in N,N-dimethyl-formamide
T=80°C; 16 h;
参考文献
Brunner, Klemens; Van Dijken, Addy; Boerner, Herbert; Bastiaansen, Jolanda J. A. M.; Kiggen, Nicole M. M.; Langeveld, Bea M. W.
Journal of the American Chemical Society, 2004 , vol. 126, # 19 p. 6035 - 6042
反应条件
1: nitric acid; acetic acid; acetic anhydride / dichloromethane / 20 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 20 °C
3: TPAP; sodium hydroxide / butanone / 70 °C
View Scheme
参考文献
Kawabata, Kohsuke; Goto, Hiromasa
Chemistry - A European Journal, 2012 , vol. 18, # 47 p. 15065 - 15072
反应条件
1: triphenylphosphine / 1,2-dichloro-benzene / 20 °C
2: TPAP; sodium hydroxide / butanone / 70 °C
View Scheme
参考文献
Kawabata, Kohsuke; Goto, Hiromasa
Chemistry - A European Journal, 2012 , vol. 18, # 47 p. 15065 - 15072
反应条件
1: 2,7-dibromo-9-octyl-9H-carbazole With n-butyllithium in tetrahydrofuran; hexane
T=-78 - 0°C; 2 h;
2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane
T=-78 - 20°C; 12 h;
参考文献
Bouchard, Jimmy; Wakim, Salem; Leclerc, Mario
Journal of Organic Chemistry, 2004 , vol. 69, # 17 p. 5705 - 5711
