6-甲基-1,5-庚二烯合成路线 （共 31 条）
反应条件
benzoylchlorobis(triphenylphosphine)palladium(II); zinc(II) chloride
T=65°C; 24 h;
参考文献
Godschalx, James; Stille, J. K.
Tetrahedron Letters, 1980 , vol. 21, p. 2599 - 2602
反应条件
phosphoric acid; iodine
Heating;
参考文献
Colonge,J.; Lasfargues,P.
Bulletin de la Societe Chimique de France, 1962 , p. 177 - 182
反应条件
tert.-butyl lithium in diethyl ether; pentane
T=-78°C; 0.0833333 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Bailey, William F.; Patricia, Jeffrey J.; Nurmi, Timo T.
Tetrahedron Letters, 1986 , vol. 27, # 17 p. 1865 - 1868
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene
T=80°C; 8 h; Title compound not separated from byproducts;
参考文献
Toi, Hiroo; Yamamoto, Yoshinori; Sonoda, Akio; Murahashi, Shun-Ichi
Tetrahedron, 1981 , vol. 37, p. 2261 - 2268
反应条件
1: Mg
2: 29 percent / SOCl2 / pyridine / -17 °C
3: Bu3SnH, azobisisobutyronitrile (AIBN) / benzene / 8 h / 80 °C
View Scheme
参考文献
Toi, Hiroo; Yamamoto, Yoshinori; Sonoda, Akio; Murahashi, Shun-Ichi
Tetrahedron, 1981 , vol. 37, p. 2261 - 2268
反应条件
benzoylchlorobis(triphenylphosphine)palladium(II); zinc(II) chloride
T=65°C; 50 h;
参考文献
Godschalx, James; Stille, J. K.
Tetrahedron Letters, 1980 , vol. 21, p. 2599 - 2602
反应条件
1: biphenyl With lithium in tetrahydrofuran
T=20°C; 0.5 h; Inert atmosphere;
2: 6-fluoro-6-methyl-1-heptene in tetrahydrofuran
T=0°C; 0.5 h; Inert atmosphere; regioselective reactionFurther stages;
参考文献
Perez, Henoc; Melero, Cristobal; Guijarro, Albert; Yus, Miguel
Tetrahedron, 2009 , vol. 65, # 52 p. 10769 - 10783
参考文献
Henne; Chanan
Journal of the American Chemical Society, 1944 , vol. 66, p. 393
反应条件
bis(diethylaluminium)sulfate in hexane; benzene
16 h; Heating;
参考文献
Hosomi, Akira; Imai, Takafumi; Endo, Masahiko; Sakurai, Hideki
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 95 - 108
反应条件
in diethyl ether; pentane
T=-78°C; 0.0833333 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Bailey, William F.; Patricia, Jeffrey J.; Nurmi, Timo T.
Tetrahedron Letters, 1986 , vol. 27, # 17 p. 1865 - 1868
