3,7,11-三甲基十二烷-3-醇合成路线 （共 10 条）
反应条件
sodium tetrahydroborate; RuCl3 monohydrate in N,N-dimethyl acetamide; water
T=0°C; 1 h; chemoselective reaction;
参考文献
Babler, James H.; Ziemke, David W.; Hamer, Robert M.
Tetrahedron Letters, 2013 , vol. 54, # 13 p. 1754 - 1757
反应条件
hydrogen; ShPAK-0.5 modified by Zn(OAc)2 + NH3 in isopropyl alcohol
T=60°C; P=5148.56 - 7355.08 Torr; 4 h;
参考文献
Tolkacheva; Kislyi; Taits; Semenov
Russian Journal of Organic Chemistry, 2002 , vol. 38, # 2 p. 150 - 152
反应条件
nickel
T=130 - 140°C; P=73550.8 - 80905.8 Torr; Hydrogenation; dextrorotatory form;
参考文献
Naves
Helvetica Chimica Acta, 1948 , vol. 31, p. 408
Perfumery and Essential Oil Record, 1948 , vol. 39, p. 280,297
Chem.Abstr., 1949 , p. 1530
反应条件
platinum(IV) oxide; acetic acid ester
T=60°C; Hydrogenation; dextrorotatory form;
参考文献
Naves
Helvetica Chimica Acta, 1946 , vol. 29, p. 1454
Helvetica Chimica Acta, 1947 , vol. 30, p. 283
反应条件
methanol; palladium on activated charcoal; hydrogen
Hydrogenation;
参考文献
Fischer,F.G.; Loewenberg
Justus Liebigs Annalen der Chemie, 1929 , vol. 475, p. 192
反应条件
1: potassium hydroxide; diethyl ether
2: palladium / Hydrogenation
3: platinum / Hydrogenation
View Scheme
参考文献
Nasarow; Kamernizkii; Achrem
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 1458,1459
J. Gen. Chem. USSR (Engl. Transl.), 1958 , vol. 28, p. 1511,1512
反应条件
platinum
Hydrogenation;
参考文献
Nasarow; Kamernizkii; Achrem
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 1458,1459
J. Gen. Chem. USSR (Engl. Transl.), 1958 , vol. 28, p. 1511,1512
反应条件
1: palladium/calcium carbonate / Hydrogenation
2: potassium hydroxide; diethyl ether
3: palladium / Hydrogenation
4: platinum / Hydrogenation
View Scheme
参考文献
Nasarow; Kamernizkii; Achrem
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 1458,1459
J. Gen. Chem. USSR (Engl. Transl.), 1958 , vol. 28, p. 1511,1512
反应条件
1: palladium-calcium carbonate; alcohol / Hydrogenation.unter Druck
2: sodium amide; diethyl ether / nachfolgenden Einleiten von Acetylen
3: hydrogen; palladium-calcium carbonate; methanol / Hydrogenation
View Scheme
参考文献
Fischer,F.G.; Loewenberg
Justus Liebigs Annalen der Chemie, 1929 , vol. 475, p. 192
参考文献
Fischer,F.G.; Loewenberg
Justus Liebigs Annalen der Chemie, 1929 , vol. 475, p. 192
