alpha-3-二甲基苄醇合成路线 （共 28 条）
反应条件
sodium hydroxide; RuCl2(PPh3)(iBu-BTP)
T=82°C; P=750.075 Torr; 7 h;
参考文献
Yu; Zeng; Sun; Deng; Dong; Chen; Wang; Pei
Journal of Organometallic Chemistry, 2007 , vol. 692, # 11 p. 2306 - 2313
反应条件
dichloro bis(acetonitrile) palladium(II); Ru2(CO)4(μ-H)(C4Ph4-COHOC-C4Ph4); water; p-benozquinone in methanol; isopropyl alcohol
T=85°C; 36 h; Inert atmosphereGlovebox; regioselective reaction;
参考文献
Yang, Yongsheng; Guo, Jiayi; Ng, Huimin; Chen, Zhiyong; Teo, Peili
Chemical Communications, 2014 , vol. 50, # 20 p. 2608 - 2611
反应条件
nickel monoaluminide in water
2 h; Heating; Title compound not separated from byproducts.;
参考文献
Ishimoto, Keiko; Mitoma, Yoshiharu; Nagashima, Satoko; Tashiro, Hideki; Prakash, G. K. Surya; Olah, George A.; Tashiro, Masashi
Chemical Communications, 2003 , # 4 p. 514 - 515
反应条件
in tetrahydrofuran
T=0°C; Inert atmosphere;
参考文献
Fernandez-Mateos, Emilio; MacIa, Beatriz; Yus, Miguel
European Journal of Organic Chemistry, 2012 , # 20 p. 3732 - 3736
反应条件
1: pyridine / 2 h / Cooling with ice
2: water; N,N-dimethyl-aniline / acetonitrile / 25 °C
View Scheme
参考文献
Yamamoto, Yutaro; Hasegawa, Hiroto; Yamataka, Hiroshi
Journal of Organic Chemistry, 2011 , vol. 76, # 11 p. 4652 - 4660
反应条件
1: hydroxylamine hydrochloride; sodium hydroxide / ethanol; water / 1 h / Reflux
2: pyridine / 2 h / Cooling with ice
3: water; N,N-dimethyl-aniline / acetonitrile / 25 °C
View Scheme
参考文献
Yamamoto, Yutaro; Hasegawa, Hiroto; Yamataka, Hiroshi
Journal of Organic Chemistry, 2011 , vol. 76, # 11 p. 4652 - 4660
参考文献
v. Auwers; Kolligs
Chemische Berichte, 1922 , vol. 55, p. 42
Show Details
Overberger et al.
Organic Syntheses, 1955 , vol. Coll. Vol. III, p. 200
反应条件
water in acetone
T=45°C; Rate constant;
参考文献
Tsuno,Y. et al.
Bulletin of the Chemical Society of Japan, 1975 , vol. 48, # 11 p. 3337 - 3346
反应条件
water; N,N-dimethyl-aniline in acetonitrile
T=25°C; Beckmann reaction; Kinetics;
参考文献
Yamamoto, Yutaro; Hasegawa, Hiroto; Yamataka, Hiroshi
Journal of Organic Chemistry, 2011 , vol. 76, # 11 p. 4652 - 4660
反应条件
(i) Mg, (ii) /BRN= 505984/; Multistep reaction;
参考文献
Tsuno,Y. et al.
Bulletin of the Chemical Society of Japan, 1975 , vol. 48, # 11 p. 3337 - 3346
