1: tris(2-methylphenyl)-1,3,5,2,4,6-trioxatriborinane With [Ni0(1,5-cyclooctadiene)2]; potassium phosphate; 4-chlorobenzophenone in tetrahydrofuran T=20°C; 2: benzaldehyde in tetrahydrofuran T=20°C;
1: With n-butyllithium in tetrahydrofuran; hexane; toluene
T=-78°C;
2: With tri-isopropoxy-borane in tetrahydrofuran; hexane; toluene
T=-78°C; 0.5 h; Further stages.;
参考文献
Iwai, Yasumasa; Gligorich, Keith M.; Sigman, Matthew S.
Angewandte Chemie - International Edition, 2008 , vol. 47, # 17 p. 3219 - 3222