KNH2; 4-pyridinecarbonitrile in acetone
T=-38°C; chemical or electrochemical reductive stimulation of the reaction of various nucleophiles, at various catalysts; MechanismRate constant;
参考文献
Amatore, Christian; Oturan, Mehmet A.; Pinson, Jean; Saveant, Jean-Michel; Thiebault, Andre
Journal of the American Chemical Society, 1985 , vol. 107, p. 3451 - 3459
1: 2-amino-benzonitrile With tetrafluoroboric acid; sodium nitrite in water
T=0°C; 0.666667 h;
2: 2-acetyloxy-1-propene With [Ru(II)(2,2’-bipyridine)3]Cl2 in N,N-dimethyl-formamide
T=20°C; 2 h; Irradiation;
Sutherland, Ronald G.; Chowdhury, Ratan L.; Piorko, Adam; Lee, Choi Chuck
Journal of the Chemical Society, Chemical Communications, 1985 , # 19 p. 1296 - 1297