3-(2-氧代丙基)苯甲腈合成路线 (共 6 条)
反应条件
tris(dibenzylideneacetone)dipalladium (0); tri-n-butyltin methoxide; N-[2'-(dicyclohexylphosphino)-1,1'-biphenyl-2-yl]-N,N-dimethylamine in toluene
T=100°C;
参考文献
Liu, Ping; Lanza Jr., Thomas J.; Jewell, James P.; Jones, Carrie P.; Hagmann, William K.; Lin, Linus S.
Tetrahedron Letters, 2003 , vol. 44, # 49 p. 8869 - 8871
反应条件
KNH2 in acetone
T=-38°C; chemical or electrochemical reductive stimulation of the reaction of various nucleophiles, at various catalysts; MechanismRate constant;
参考文献
Amatore, Christian; Oturan, Mehmet A.; Pinson, Jean; Saveant, Jean-Michel; Thiebault, Andre
Journal of the American Chemical Society, 1985 , vol. 107, p. 3451 - 3459
反应条件
1: n-BuNH2 / toluene
2: 1.) Fe/FeCl3; 2.) H2O
View Scheme
参考文献
Gardrat, C.
Bulletin des Societes Chimiques Belges, 1984 , vol. 93, # 10 p. 897 - 902
反应条件
manganese triacetate in acetic acid
Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Gardrat, C.
Bulletin des Societes Chimiques Belges, 1984 , vol. 93, # 10 p. 897 - 902
反应条件
water; iron(III) chloride; iron
Multistep reaction;
参考文献
Gardrat, C.
Bulletin des Societes Chimiques Belges, 1984 , vol. 93, # 10 p. 897 - 902
反应条件
manganese triacetate in acetic acid
T=60°C; also in the presence of benzene at 70 deg C (relative reactivity); Rate constant;
参考文献
Vinogradova, M. G.; Min, R. S.; Aksenov, V. S.; Nikishin, G. I.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, p. 1760 - 1765
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 9 p. 1994 - 1999