3,6-二羟基-2-[(1E,3E,5E)-十一碳-1,3,5-三烯基]苯甲醛合成路线 （共 24 条）
反应条件
1: 82 percent / acetonitrile / 48 h / Ambient temperature
2: 1.) n-butyl-lithium, 3.) iodine
3: 94 percent / lithium aluminium hydride / diethyl ether / 12 h / Ambient temperature
4: 59 percent / oxalyl chloride, dimethyl sulphoxide / CH2Cl2
5: 5 percent / boron tri-iodide, ethylene / CH2Cl2 / -20 °C
View Scheme
参考文献
Harwood, Laurence M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 11 p. 2577 - 2582
反应条件
1: 59 percent / oxalyl chloride, dimethyl sulphoxide / CH2Cl2
2: 5 percent / boron tri-iodide, ethylene / CH2Cl2 / -20 °C
View Scheme
参考文献
Harwood, Laurence M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 11 p. 2577 - 2582
反应条件
1: 94 percent / lithium aluminium hydride / diethyl ether / 12 h / Ambient temperature
2: 59 percent / oxalyl chloride, dimethyl sulphoxide / CH2Cl2
3: 5 percent / boron tri-iodide, ethylene / CH2Cl2 / -20 °C
View Scheme
参考文献
Harwood, Laurence M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 11 p. 2577 - 2582
反应条件
1: 1.) n-butyl-lithium, 3.) iodine
2: 94 percent / lithium aluminium hydride / diethyl ether / 12 h / Ambient temperature
3: 59 percent / oxalyl chloride, dimethyl sulphoxide / CH2Cl2
4: 5 percent / boron tri-iodide, ethylene / CH2Cl2 / -20 °C
View Scheme
参考文献
Harwood, Laurence M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 11 p. 2577 - 2582
