1-Cbz-6-(4,4,5,5-四甲基-[1,3,2]二噁硼烷-2-基)-1,2,3,4-四氢吡啶合成路线 （共 7 条）
反应条件
potassium carbonate; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride in 1,4-dioxane
T=90°C; 7 h;
参考文献
Ferrali, Alessandro; Guarna, Antonio; Lo Galbo, Fabrizio; Occhiato, Ernesto G.
Tetrahedron Letters, 2004 , vol. 45, # 27 p. 5271 - 5274
反应条件
bis-triphenylphosphine-palladium(II) chloride; potassium carbonate; triphenylphosphine in 1,4-dioxane
T=90°C; 7 h;
参考文献
Occhiato, Ernesto G.; Lo Galbo, Fabrizio; Guarna, Antonio
Journal of Organic Chemistry, 2005 , vol. 70, # 18 p. 7324 - 7330
反应条件
bis-triphenylphosphine-palladium(II) chloride; potassium carbonate; triphenylphosphine in 1,4-dioxane
T=90°C; 5 h;
参考文献
Occhiato, Ernesto G.; Lo Galbo, Fabrizio; Guarna, Antonio
Journal of Organic Chemistry, 2005 , vol. 70, # 18 p. 7324 - 7330
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triethylamine in 1,4-dioxane
T=50°C; 2 h; Product distribution; Further Variations:ReagentsTemperatures;
参考文献
Occhiato, Ernesto G.; Lo Galbo, Fabrizio; Guarna, Antonio
Journal of Organic Chemistry, 2005 , vol. 70, # 18 p. 7324 - 7330
反应条件
1.1: KHMDS / tetrahydrofuran; toluene / 1.5 h / -78 °C
1.2: 80 percent / tetrahydrofuran; toluene / 2 h / -78 - 20 °C
2.1: 85 percent / (Ph3P)2PdCl2; Ph3P; K2CO3 / dioxane / 7 h / 90 °C
View Scheme
参考文献
Occhiato, Ernesto G.; Lo Galbo, Fabrizio; Guarna, Antonio
Journal of Organic Chemistry, 2005 , vol. 70, # 18 p. 7324 - 7330
反应条件
bromobenzene; potassium carbonate; trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) in toluene
T=110°C; 4 h;
参考文献
Ferrali, Alessandro; Guarna, Antonio; Lo Galbo, Fabrizio; Occhiato, Ernesto G.
Tetrahedron Letters, 2004 , vol. 45, # 27 p. 5271 - 5274
反应条件
potassium phosphate; triphenylphosphine; palladium diacetate in 1,4-dioxane
T=100°C; 1.5 h; Product distribution; Further Variations:ReagentsSolventsTemperatures;
参考文献
Ferrali, Alessandro; Guarna, Antonio; Lo Galbo, Fabrizio; Occhiato, Ernesto G.
Tetrahedron Letters, 2004 , vol. 45, # 27 p. 5271 - 5274
