2,4,6-三叔丁基苯酚合成路线 （共 262 条）
反应条件
oxygen; cobalt(II)salen in dichloromethane
T=20°C; Oxidation; 3 h; Product distribution; Further Variations:Catalysts;
参考文献
Knaudt, Jutta; Foerster, Stefan; Bartsch, Ulrich; Rieker, Anton; Jaeger, Ernst-G.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2000 , vol. 55, # 1 p. 86 - 93
反应条件
Mn(tpp)Cl-Bu4NBH4 in toluene
4 h; Yield given. Yields of byproduct given;
参考文献
Frostin-Rio, Maryvonne; Pujol, Daniele; Bied-Charreton, Claude; Perree-Fauvet, Martine; Gaudemer, Alain
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , p. 1971 - 1980
反应条件
Co(salnp); oxygen in pyridine; chloroform
24 h; Yield given. Yields of byproduct given;
参考文献
Frostin-Rio, Maryvonne; Pujol, Daniele; Bied-Charreton, Claude; Perree-Fauvet, Martine; Gaudemer, Alain
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , p. 1971 - 1980
反应条件
oxygen; manganese triacetate in methanol
T=20°C; further reagents; Product distribution;
参考文献
Batanov, I. A.; Nikiforov, G. A.; Ershov, V. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 2 p. 325 - 329
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 2 p. 359 - 364
反应条件
K[Co(salen)CO3] in ethanol
12 h; Ambient temperatureother catalyst; Product distribution;
参考文献
Aimoto, Yuko; Kanda, Wakako; Meguro, Sadatoshi; Miyahara, Yuji
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 2 p. 646 - 650
反应条件
Co(salN-Medpt); oxygen in toluene
24 h; influence of the catalyst nature, solvent, and time of reaction; Product distributionMechanism;
参考文献
Frostin-Rio, Maryvonne; Pujol, Daniele; Bied-Charreton, Claude; Perree-Fauvet, Martine; Gaudemer, Alain
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , p. 1971 - 1980
反应条件
potassium hydride in tetrahydrofuran
1.)1 hr, 5 degC 2.)1 hr, RT; Yield given. Title compound not separated from byproducts;
参考文献
Barton, Derek H. R.; Finet, Jean-Pierre; Gianotti, Charles; Halley, Frank
Tetrahedron, 1988 , vol. 44, # 14 p. 4483 - 4494
反应条件
1: (i) O2, aq. KOH, EtOH, (ii) Me2S
2: tBuLi / pentane; diethyl ether
View Scheme
参考文献
Nishinaga,A. et al.
Chemische Berichte, 1976 , vol. 109, p. 1530 - 1548
反应条件
1: With tri(n-propyl)amine
T=60 - 120°C; 3 h;
2: With 1,8-diazabicyclo[5.4.0]undec-7-ene
T=26 - 120°C; 1 h;
参考文献
General Electric Company
Patent: US2004/59151 A1, 2004 ;
Location in patent: Page 3; 4 ;
反应条件
potassium hydride in tetrahydrofuran
1.)1 hr, 5 degC 2.)1 hr, RT; Yield given. Title compound not separated from byproducts;
参考文献
Barton, Derek H. R.; Finet, Jean-Pierre; Gianotti, Charles; Halley, Frank
Tetrahedron, 1988 , vol. 44, # 14 p. 4483 - 4494
