2-三甲基甲硅烷基乙基苯基砜合成路线 （共 18 条）
反应条件
n-butyllithium; sodium hydride 1.) dimethoxyethane, -78 deg C -> r.t., 2 h, 2.) reflux, 30 min.; Yield given. Multistep reaction;
参考文献
Kabat, Marek M.; Wicha, Jerzy
Tetrahedron Letters, 1991 , vol. 32, # 8 p. 1073 - 1076
反应条件
in N,N-dimethyl-formamide T=30°C; Rate constant;
参考文献
Jones, Steven L.; Stirling, Charles J. M.
Journal of the Chemical Society, Chemical Communications, 1988 , # 17 p. 1153 - 1154
反应条件
dihydrogen peroxide in acetic acid
T=100°C; 2 h;
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 19 p. 1963 - 1966
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran; hexane
T=-40°C;
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
反应条件
1: With 1,10-phenanthroline; (CuOTf)2.C6H6
T=100°C; Inert atmosphere;
2: With toluene-4-sulfonic acid in water
T=20°C; 0.5 h; Inert atmosphere;
参考文献
Iannazzo, Laura; Molander, Gary A.
European Journal of Organic Chemistry, 2012 , # 26 p. 4923 - 4926,4
反应条件
1: AIBN / 1 h / 90 °C
2: 81 percent / (NH4)6Mo7O24*7H2O, 30percent H2O2 / methanol / 16 h / 20 °C
View Scheme
参考文献
Menichetti, Stefano; Stirling, Charles J. M.
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 13 p. 1511 - 1515
反应条件
1: 70 percent / cupric chloride / CH2Cl2; acetonitrile / 10 h / 130 °C
2: 60 percent / Et3N / benzene / 48 h / 25 °C
3: 1.) bis(1,5-cyclooctadiene)nickel ((COD)2Ni); 2.) HOAc
View Scheme
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
反应条件
1: 88 percent / 1.) bis(1,5-cyclooctadiene)nickel ((COD)2Ni); 2.) glacial HOAc / tetrahydrofuran / 21 h / 25 °C
2: 1.) bis(1,5-cyclooctadiene)nickel ((COD)2Ni); 2.) HOAc
View Scheme
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
反应条件
1: 75 percent / AlCl3 / CH2Cl2 / 12 h / Ambient temperature
2: 88 percent / 1.) bis(1,5-cyclooctadiene)nickel ((COD)2Ni); 2.) glacial HOAc / tetrahydrofuran / 21 h / 25 °C
3: 1.) bis(1,5-cyclooctadiene)nickel ((COD)2Ni); 2.) HOAc
View Scheme
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
反应条件
1: 60 percent / Et3N / benzene / 48 h / 25 °C
2: 1.) bis(1,5-cyclooctadiene)nickel ((COD)2Ni); 2.) HOAc
View Scheme
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
