2-三甲基甲硅烷基乙基苯基砜合成路线 （共 18 条）
反应条件
1: 99.2 percent / azoisobutyrinitrile / 90 °C
2: 99.2 percent / H2O2 / acetic acid / 2 h / 100 °C
View Scheme
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 19 p. 1963 - 1966
反应条件
bis(1,5-cyclooctadiene)nickel (0); acetic acid
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
反应条件
bis(1,5-cyclooctadiene)nickel (0); acetic acid
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
反应条件
1: n-butyllithium / 1.) hexane, ethyl ether, -70 deg C, 25 min, 2.) from - 70 deg C up to room temperature in 20 min
2: diethyl ether / 1.) -10 deg C, 2.) reflux 25 min
3: sodium amalgam, disodium hydrogen phosphate / methanol / 1 h / 0 °C
View Scheme
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 19 p. 1963 - 1966
反应条件
1: n-butyllithium / 1.) hexane, ethyl ether, -70 deg C, 25 min, 2.) from - 70 deg C up to room temperature in 20 min
2: diethyl ether / 1.) -10 deg C, 2.) reflux 25 min
3: sodium amalgam, disodium hydrogen phosphate / methanol / 1 h / 0 °C
View Scheme
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 19 p. 1963 - 1966
反应条件
n-butyllithium; sodium hydride
1.) dimethoxyethane, -78 deg C -> r.t., 2.) reflux, 30 min.; Yield given. Multistep reaction;
参考文献
Kabat, Marek M.; Wicha, Jerzy
Tetrahedron Letters, 1991 , vol. 32, # 8 p. 1073 - 1076
反应条件
1: n-butyllithium / 1.) hexane, ethyl ether, -70 deg C, 25 min, 2.) from - 70 deg C up to room temperature in 20 min
2: diethyl ether / 1.) -10 deg C, 2.) reflux 25 min
3: sodium amalgam, disodium hydrogen phosphate / methanol / 1 h / 0 °C
View Scheme
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 19 p. 1963 - 1966
反应条件
1: n-butyllithium / hexane; diethyl ether / -70 °C
2: 97 percent / CrO3, H2SO4 / acetone / 1 h / 0 - 5 °C
3: 99 percent / KOH, NaOCl / dioxane / 2.5 h
4: n-butyllithium / hexane; diethyl ether / 0.5 h / -70 °C
5: tetra-n-butylammonium fluoride / tetrahydrofuran / 0.17 h / 25 °C
View Scheme
参考文献
Hsiao, C-N.; Shechter, H.
Tetrahedron Letters, 1982 , vol. 23, # 34 p. 3455 - 3458
