2,4,6-三丁基环硼氧烷合成路线 （共 37 条）
参考文献
Gmelin Handbook: B: B-Verb.9, 5.2.3, page 182 - 189
参考文献
Gmelin Handbook: B: B-Verb.13, 4.7.2.2, page 189 - 196
参考文献
Gmelin Handbook: B: B-Verb.13, 4.7.2.2, page 189 - 196
参考文献
Hennion et al.
Journal of the American Chemical Society, 1957 , vol. 79, p. 5149
反应条件
in neat (no solvent)
boiling equimolar amounts of educts for 40h;; distn. in vac.;;
参考文献
Hennion et al.
Journal of the American Chemical Society, 1957 , vol. 79, p. 5194
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Gmelin Handbook: B: B-Verb.13, 4.7.2.2, page 189 - 196
反应条件
sulfuric acid; benzene in diethyl ether
byproducts: H2O; addn. of 1.66mol RMgBr in ether to 0.53mol B(OCH3)3 in ether at -75°C, stiiring at -70°C (4h), warming slowly to -10°C, hydrolysis with 10percent H2SO4, separation of organic phase, removal of solvent, boiling of residue with C6H6;;
参考文献
McCusker et al.
Journal of the American Chemical Society, 1957 , vol. 79, p. 5179
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Gmelin Handbook: B: B-Verb.13, 4.7.2.2, page 189 - 196
反应条件
in neat (no solvent)
refluxing, 24h;;
参考文献
Hennion et al.
Journal of the American Chemical Society, 1957 , vol. 79, p. 5194
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Gmelin Handbook: B: B-Verb.13, 4.7.2.2, page 189 - 196
参考文献
Hennion et al.
Journal of the American Chemical Society, 1957 , vol. 79, p. 5149
反应条件
Erhitzen unter Vermindertem Druck;
参考文献
Snyder; Kuck; Johnson
Journal of the American Chemical Society, 1938 , vol. 60, p. 110
反应条件
in neat (no solvent)
byproducts: B(OCH3)3; heating equimolar amounts of educts (149-197°C) for 1h, removal of generated B(OCH3)3 in the course of react.;; isomeric mixture after distn. in vac. (isomerization); pure (B(s-C4H9)O)3 after redistn. of the first fraction;;
参考文献
Mc Cusker; Bright
Journal of Organic Chemistry, 1964 , vol. 29, p. 2093
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Gmelin Handbook: B: B-Verb.13, 4.7.2.2, page 189 - 196
