3,4'-二甲基-1,1'-联苯合成路线 （共 62 条）
反应条件
potassium acetate; 18-crown-6 ether
1.5 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Beadle, James R.; Korzeniowsky, Stephen H.; Rosenberg, David E.; Garcia-Slanga, Blanche J.; Gokel, George W.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1594 - 1603
反应条件
phosphorus pentoxide
T=260 - 300°C;
参考文献
Skvarchenko,V.R. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1962 , vol. 32, # 1 p. 217 - 222,211 - 215
反应条件
Ni(PPh3)4
Kumada coupling reaction;
参考文献
Lipshutz, Bruce H.; Blomgren, Peter A.
Organic Letters, 2001 , vol. 3, # 12 p. 1869 - 1871
反应条件
1: sodium sulfate / tetrahydrofuran / 24 h / 20 °C / |Schlenk technique; |Inert atmosphere
2: bis-triphenylphosphine-palladium(II) chloride; potassium hydroxide / neat (no solvent) / 24 h / 110 °C / |Schlenk technique; |Inert atmosphere
View Scheme
参考文献
Asachenko, Andrey F.; Sorochkina, Kristina R.; Dzhevakov, Pavel B.; Topchiy, Maxim A.; Nechaev, Mikhail S.
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3553 - 3557
反应条件
sodium hexabromoplatinate(IV) in water; trifluoroacetic acid
T=85°C;
参考文献
Shul'pin, G. B.; Deiko, S. A.; Yatsimirskii, A. K.
J. Gen. Chem. USSR (Engl. Transl.), 1991 , vol. 61, # 4.1 p. 822 - 824,742 - 744
反应条件
1: Al(OiPr)3
2: (i) polyphosphoric acid, (ii) sulfur
View Scheme
参考文献
Colonge,J.; Brunie,J.-C.
Bulletin de la Societe Chimique de France, 1963 , p. 42 - 46
反应条件
Tl(OCOCF3)3; palladium diacetate
T=70°C; 40 h; variation of amount of Pd(II); without TTFA; in the presence of thallium(III) acetate sesquihydrate and TFA; Product distributionRate constant;
参考文献
Yatsimirsky, Anatoly K.; Deiko, Sergei A.; Ryabov, Alexander D.
Tetrahedron, 1983 , vol. 39, # 14 p. 2381 - 2392
反应条件
Rh(I)Cl(CO)(PMe3)2
16.5 h; Ambient temperatureIrradiation; Further byproducts given;
参考文献
Sakakura, Toshiyasu; Sodeyama, Touru; Tokunaga, Yuko; Tanaka, Masato
Chemistry Letters, 1987 , p. 2211 - 2214
反应条件
Rh(I)Cl(CO)(PMe3)2
16.5 h; Ambient temperatureIrradiation; Product distributionMechanism;
参考文献
Sakakura, Toshiyasu; Sodeyama, Touru; Tokunaga, Yuko; Tanaka, Masato
Chemistry Letters, 1987 , p. 2211 - 2214
反应条件
Rh(I)Cl(CO)(PMe3)2
16.5 h; Ambient temperatureIrradiation; Further byproducts given;
参考文献
Sakakura, Toshiyasu; Sodeyama, Touru; Tokunaga, Yuko; Tanaka, Masato
Chemistry Letters, 1987 , p. 2211 - 2214
