3,5-双(三氟甲基)苯硼酸合成路线 （共 12 条）
反应条件
1.1: 4,4'-di-tert-butyl-2,2'-bipyridine / [Ir(COD)(OMe)]2 / tetrahydrofuran / 16 h / 80 °C 2.1: sodium periodate / tetrahydrofuran; H2O / 0.25 h 2.2: HCl / H2O; tetrahydrofuran / 4 h View Scheme
参考文献
Organic Letters, , vol. 9, # 5 p. 757 - 760
反应条件
1: With n-butyllithium in tetrahydrofuran T=-78°C; 3 h; 2: With boric acid trimethyl ester in tetrahydrofuran T=-78 - 20°C; 3: With hydrogenchloride in tetrahydrofuran; water 1 h;
参考文献
Journal of Nanoscience and Nanotechnology, , vol. 10, # 8 p. 5153 - 5160
反应条件
1: With sodium periodate in tetrahydrofuran; water 0.25 h; 2: With hydrogenchloride in tetrahydrofuran; water 4 h;
参考文献
Organic Letters, , vol. 9, # 5 p. 757 - 760
反应条件
glass or Cs2CO3 in tetrahydrofuran; water Kinetics; hydrolysis at 55°C in THF/H2O in the presence of glass powder or Cs2CO3; not isolated;
参考文献
Journal of the American Chemical Society, , vol. 134, # 17 p. 7431 - 7441
反应条件
potassium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether; water T=80 - 90°C; Suzuki cross-coupling reaction; 16 h;
参考文献
Journal of Organometallic Chemistry, , vol. 692, # 22 p. 4809 - 4827
反应条件
sodium carbonate in tetrahydrofuran 16 h; Inert atmosphere;
参考文献
Kasai, Shizuo; Kamaura, Masahiro; Cho, Nobuo
Patent: US2011/251187 A1, 2011 ;
Location in patent: Page/Page column 54 ;
反应条件
tris-(dibenzylideneacetone)dipalladium(0); sodium carbonate; triphenylphosphine in ethanol; water; toluene
T=90°C; 16 h; Inert atmosphereAutoclave;
参考文献
Ditri, Treffly B.; Carpenter, Alex E.; Ripatti, Donald S.; Moore, Curtis E.; Rheingold, Arnold. L.; Figueroa, Joshua S.
Inorganic Chemistry, 2013 , vol. 52, # 22 p. 13216 - 13229
反应条件
1: sodium carbonate / tetrahydrofuran / 16 h / Inert atmosphere
2: ethanol; sodium tetrahydroborate / 1 h / 20 °C
View Scheme
参考文献
Kasai, Shizuo; Kamaura, Masahiro; Cho, Nobuo
Patent: US2011/251187 A1, 2011 ;
反应条件
cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0) in 1,4-dioxane
T=20°C; 12 h;
参考文献
Ionkin, Alex Sergey
Patent: US2006/281923 A1, 2006 ;
Location in patent: Page/Page column 6 ;
反应条件
cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0) in 1,4-dioxane
T=20°C; 12 h;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY
Patent: EP2016154 B1, 2012 ;
Location in patent: Page/Page column 6 ;
